Characterisation and In Situ Age Determination of Zircon Inclusions in Sapphires from Muling, North-East China

In recent decades, blue and fancy-colour sapphires have been gathered from secondary deposits derived from Tertiary basalts in the Muling area of north-eastern China. In this article, zircon inclusions in the blue sapphires were studied to characterise their morphology and structure, as well as to obtain the age of the host sapphires. The zircon inclusions in the studied samples were euhedral and transparent, and their dominant morphology was similar to that of typical zircon inclusions in sapphires associated with alkali basalts. Raman spectroscopy of the zircons showed only slight radiation damage, and cathodoluminescence images revealed two distinctive zoning patterns (in their cores and rims). LA-ICP-MS analyses of the zircon rims showed typical magmatic Th/U ratios. In situ U-Pb dating of the zircon rims yielded ages of 9 to 8 Ma-which is the inferred upper limit of the formation age of the host sapphires-while cores had much older ages that exceeded 110 Ma (i.e. an inherited age component). The 9-8 Ma sapphire age coincides with Late Miocene basaltic eruptions in the Dunhua-Mishan graben. Age dating of zircon inclusions in the Muling sapphires helps elucidate their geological origin and provides useful information for the provenance determination of gem corundum.