Preparation and Characterization of Cellulose Nanocrystals from Bamboos and Their Application in Cassava Starch-Based Film

被引:26
作者
Thipchai, Parichat [1 ]
Punyodom, Winita [2 ,3 ]
Jantanasakulwong, Kittisak [3 ,4 ,5 ]
Thanakkasaranee, Sarinthip [3 ,4 ,5 ]
Hinmo, Sasina [6 ]
Pratinthong, Kanticha [6 ]
Kasi, Gopinath [4 ]
Rachtanapun, Pornchai [3 ,4 ,5 ]
机构
[1] Chiang Mai Univ, Fac Sci, Philosophy Program Nanosci & Nanotechnol, Int Program Interdisciplinary, Chiang Mai 50200, Thailand
[2] Chiang Mai Univ, Fac Sci, Dept Chem, Chiang Mai 50200, Thailand
[3] Chiang Mai Univ, Ctr Excellence Mat Sci & Technol, Chiang Mai 50200, Thailand
[4] Chiang Mai Univ, Fac Agroind, Sch Agroind, Div Packaging Technol, Chiang Mai 50100, Thailand
[5] Chiang Mai Univ, Cluster Agro Biocircular Green Ind Agro BCG, Chiang Mai 50100, Thailand
[6] Chiang Mai Univ, Fac Sci, Master Sci Program Phys Chem, Chiang Mai 50200, Thailand
关键词
bamboo; biopolymer; cassava starch; cellulose nanocrystals; composite film; ultrasonication; PHYSICOCHEMICAL PROPERTIES; BIO-NANOCOMPOSITES; BARRIER PROPERTIES; NANOCELLULOSE; WASTE; NANOFIBRILS; COMPOSITES;
D O I
10.3390/polym15122622
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Cellulose from different species of bamboo (Thyrsostachys siamesi Gamble, Dendrocalamus sericeus Munro (DSM), Bambusa logispatha, and Bambusa sp.) was converted to cellulose nanocrystals (CNCs) by a chemical-mechanical method. First, bamboo fibers were pre-treated (removal of lignin and hemicellulose) to obtain cellulose. Next, the cellulose was hydrolyzed with sulfuric acid using ultrasonication to obtain CNCs. The diameters of CNCs are in the range of 11-375 nm. The CNCs from DSM showed the highest yield and crystallinity, which was chosen in the film fabrication. The plasticized cassava starch-based films with various amounts (0-0.6 g) of CNCs (from DSM) were prepared and characterized. As the number of CNCs in cassava starch-based films increased, water solubility and the water vapor permeability of CNCs decreased. In addition, the atomic force microscope of the nanocomposite films showed that CNC particles were dispersed uniformly on the surface of cassava starch-based film at 0.2 and 0.4 g content. However, the number of CNCs at 0.6 g resulted in more CNC agglomeration in cassava starch-based films. The 0.4 g CNC in cassava starch-based film was found to have the highest tensile strength (4.2 MPa). Cassava starch-incorporated CNCs from bamboo film can be applied as a biodegradable packaging material.
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页数:21
相关论文
共 73 条
[11]   Addition of wheat straw nanofibrils to improve the mechanical and barrier properties of cassava starch-based bionanocomposites [J].
do Lago, Rafael Carvalho ;
Matos de Oliveira, Ana Lazara ;
dos Santos, Allan de Amorim ;
Mauricio Zitha, Elidio Zaidine ;
Nunes Carvalho, Elisangela Elena ;
Denzin Tonoli, Gustavo Henrique ;
de Barros Vilas Boas, Eduardo Valerio .
INDUSTRIAL CROPS AND PRODUCTS, 2021, 170
[12]   Preparation of spherical nanocellulose from Gai bamboo and mechanical properties of chitosan/nanocellulose composite [J].
Do, Thi Vi Vi ;
Tran, Ngoc Bao An ;
Nguyen-Thai, Ngoc Uyen .
POLYMER COMPOSITES, 2023, 44 (04) :2287-2295
[13]   Improvement of starch film performances using cellulose microfibrils [J].
Dufresne, A ;
Vignon, MR .
MACROMOLECULES, 1998, 31 (08) :2693-2696
[14]   Characteristics of cellulose extracted from Josapine pineapple leaf fibre after alkali treatment followed by extensive bleaching [J].
Fareez, Ismail Muhamad ;
Ibrahim, Nur Ain ;
Yaacob, Wan Mohd Hanif Wan ;
Razali, Nur Amira Mamat ;
Jasni, Ainil Hawa ;
Aziz, Fauziah Abdul .
CELLULOSE, 2018, 25 (08) :4407-4421
[15]  
Lomelí-Ramírez MG, 2014, BIORESOURCES, V9, P2960
[16]   Cellulose Nanocrystals: Chemistry, Self-Assembly, and Applications [J].
Habibi, Youssef ;
Lucia, Lucian A. ;
Rojas, Orlando J. .
CHEMICAL REVIEWS, 2010, 110 (06) :3479-3500
[17]   Extraction and characterization of novel ultrastrong and tough natural cellulosic fiber bundles from manau rattan (Calamus manan) [J].
Han, Xiaoshuai ;
Ding, Linhu ;
Tian, Zhiwei ;
Wu, Weijie ;
Jiang, Shaohua .
INDUSTRIAL CROPS AND PRODUCTS, 2021, 173
[18]  
He Wen He Wen, 2013, Journal of Nanjing Forestry University (Natural Sciences Edition), V37, P95
[19]  
Hong B, 2016, CELL CHEM TECHNOL, V50, P225
[20]   Preparation of cellulose nanocrystals and carboxylated cellulose nanocrystals from borer powder of bamboo [J].
Hu, Yang ;
Tang, Lirong ;
Lu, Qilin ;
Wang, Siqun ;
Chen, Xuerong ;
Huang, Biao .
CELLULOSE, 2014, 21 (03) :1611-1618