Facile Preparation Strategy of Novel Carbon Dots with Aggregation-Induced Emission and Room-Temperature Phosphorescence Characteristics

被引:20
作者
Ding, Liu [1 ,2 ]
Jin, Xilang [1 ,3 ]
Gao, Yuchong [4 ]
Wu, Jinlong [2 ]
Ai, Taotao [2 ]
Zhou, Hongwei [1 ]
Chen, Xinyu [1 ]
Zhang, Xinyu [1 ]
Chen, Weixing [1 ]
机构
[1] Xian Technol Univ, Engn Res Ctr Light Stabilizers Polymer Mat, Sch Mat & Chem Engn, Shaanxi Key Lab Photoelect Funct Mat & Devices,Uni, Xian 710021, Peoples R China
[2] Shaanxi Univ Technol, Sch Mat Sci & Engn, Hanzhong 723000, Peoples R China
[3] Yulin Boyi Jingking Res Inst Ind Technol Dev Res, Yulin 719054, Peoples R China
[4] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
基金
中国国家自然科学基金;
关键词
aggregation-induced emission; dual fluorescence emission; information encryption; room-temperature phosphorescence; FLUORESCENCE;
D O I
10.1002/adom.202202349
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
As one of the most promising fluorescent nanomaterials, carbon dots (CDs) are extensively studied. Nevertheless, one-pot synthesis methods for CDs with both dual emission aggregation-induced emission (AIE) and room-temperature phosphorescence (RTP) could lead to significant breakthrough in extensive application fields. Herein, a new class of CDs (E-CCDs) with reversible luminescence (blue dissolved fluorescence and red AIE) and RTP behavior is obtained with an eco-friendly, low-cost one-pot solvothermal method. E-CCDs exhibit dual fluorescence emission at 460 (Em-1) and 600 nm (Em-2), which is related to different emission centers. The addition of cyanic acid enhances the RTP behavior with a lifetime of 1.17 s, which lasts for approximate to 9 s to the naked eye. Based on the unique fluorescence and phosphorescence characteristics of CDs, E-CCDs can be potentially used for fingerprint detection and information encryption.
引用
收藏
页数:8
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