Photocatalytic CO2 reduction using metal and nonmetal doped TiO2 and its mechanism

被引：9

作者：

Khan, Nishat ^{[1
]}

Sapi, Andras ^{[2
]}

Arora, Isha ^{[1
]}

Sagadevan, Suresh ^{[3
]}

Chandra, Amrish ^{[4
]}

Garg, Seema ^{[1
]}

机构：

[1] Amity Univ, Amity Inst Appl Sci, Dept Chem, Sect 125, Noida 201313, Uttar Pradesh, India

[2] Univ Szeged, Dept Appl & Environm Chem, Szeged, Hungary

[3] Univ Malaya, Nanotechnol & Catalysis Res Ctr, Kuala Lumpur 50603, Malaysia

[4] Sharda Univ, Sharda Sch Pharm, Greater Noida 201310, Uttar Pradesh, India

来源：

REACTION KINETICS MECHANISMS AND CATALYSIS | 2024年 / 137卷 / 02期

关键词：

Photocatalyst; Co-catalyst; Platinum nanoparticles; Sensitization; Heterojunction formation; GAS SHIFT REACTION; CARBON-DIOXIDE; RECENT PROGRESS; COMPOSITE PHOTOCATALYSTS; CATALYSTS; WATER; PHOTOREDUCTION; H2O; NANOCOMPOSITES; HYDROGENATION;

D O I：

10.1007/s11144-024-02601-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photocatalysis based on semiconductors has recently sparked significant scientific interest due to its numerous applications in environmental beneficiaries and renewable energy generation. TiO2 reported in the literature is UV-active due to its larger band gap. Platinum (Pt) metal combined with titanium dioxide (TiO2) photocatalyst, is widely used as an effective photocatalyst for carbon dioxide hydrogenation. Therefore, this Review study aims to enhance the activity of photocatalysts, employing distinct modification strategies to decrease band gap and make the photocatalyst efficient in absorbing visible light range. This review summarises the photocatalytic mechanism, as well as numerous modification techniques, for changing UV light-active photocatalysts to visible light active as well as increasing visible light absorption. These modification techniques include variability via using various semiconducting materials as well as metal and nonmetal doping, sensitizer doping, a heterojunction formation as well as semiconductors coupling, co-catalyst loading, and defect formation.

引用

页码：629 / 655

页数：27

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