Dynamic Conducting Polymer Plasmonics and Metasurfaces

被引:17
作者
Chen, Shangzhi [1 ]
Jonsson, Magnus P. [1 ,2 ]
机构
[1] Link ping Univ, Dept Sci & Technol ITN, Lab Organ Elect, S-60174 Norrkoping, Sweden
[2] Wallenberg Res Ctr Stellenbosch Univ, Stellenbosch Inst Adv Study STIAS, ZA-7600 Stellenbosch, South Africa
基金
瑞典研究理事会;
关键词
conducting polymers; plasmonics; metasurfaces; redox-tunable; nanofabrication; VAPOR-PHASE POLYMERIZATION; REFLECTANCE; METAL; BIPOLARONS; CONSTANTS; DISCOVERY; PEDOTPSS; POLARONS; SINGLE; STATE;
D O I
10.1021/acsphotonics.2c01847
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Metals have been the dominant plasmonic materials for decades, but they suffer from limited tunability. By contrast, conducting polymers offer exceptional tunability and were recently introduced as a new category of dynamic plasmonic materials. Their charge carrier density can be drastically modulated via their redox state, offering reversible and gradual transitions between optically metallic and dielectric behavior. Nanoantennas made from conducting polymers can therefore be reversibly turned off and on again. This enables phase gradient metasurfaces with tunable functionalities, holding promise for applications such as video holograms. In this Perspective, we discuss the emergence of dynamic conducting polymer plasmonics as a new research direction, including recent developments, remaining challenges, and opportunities for future research. We hope that this Perspective will encourage more researchers to join the journey and contribute toward a rapid development of this interdisciplinary field.
引用
收藏
页码:571 / 581
页数:11
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