Preparation of MgAl2O4 Spinel Activated with Manganese Ions by Self-Propagating High-Temperature Synthesis

被引：3

作者：

Tomilin, O. B. ^{[1
]}

Muryumin, E. E. ^{[1
]}

Fadin, M. V. ^{[1
]}

机构：

[1] Natl Res Mordovia State Univ, Saransk 430005, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 68卷 / 03期

关键词：

luminophor; LEDs; thermal effect; ELECTRON-PARAMAGNETIC-RESONANCE; PHOTOLUMINESCENCE PROPERTIES; CAALSIN3EU2+ PHOSPHOR; COMBUSTION SYNTHESIS; OPTICAL-PROPERTIES; LUMINESCENCE; GREEN; EPR; SPECTRA; MN2+;

D O I：

10.1134/S0036023622602616

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A self-propagating high-temperature synthesis of samples of the MgAl2O4 : Mn2+ luminophor has been carried out using the thermal effect of the reaction between aluminum and sodium perchlorate. Using energy dispersive analysis, the qualitative and quantitative composition of the luminophor has been established. To determine the degree of oxidation of manganese ions, the EPR spectra of the luminophor have been studied. The phase composition of the synthesis products has been established by X-ray diffraction, and the luminescent properties have been characterized by the excitation and emission spectra. The influence of the manganese content, as well as the Al : Al2O3 ratio in the charge, on the luminescent characteristics of the synthesized product has been studied.

引用

页码：256 / 262

页数：7

共 47 条

[41] Synthesis of nano-size BaMgAl10O17:Eu2+ blue phosphor by a rapid exothermic reaction [J].

Won, C. W. ;

Nersisyan, H. H. ;

Won, H. I. ;

Kwon, S. J. ;

Kim, H. Y. ;

Seo, S. Y. .

JOURNAL OF LUMINESCENCE, 2010, 130 (04) :678-681

[42] Phosphors in phosphor-converted white light-emitting diodes Recent advances in materials, techniques and properties [J].

Ye, S. ;

Xiao, F. ;

Pan, Y. X. ;

Ma, Y. Y. ;

Zhang, Q. Y. .

MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2010, 71 (01) :1-34

[43] Emission properties of EU2+, Mn2+ in MAl2Si2O8 (M = Sr, Ba) [J].

Ye, Shi ;

Liu, Zhong-Shi ;

Wang, Xiu-Teng ;

Wang, Jia-Guo ;

Wang, Ling-Xuan ;

Jing, Xi-Ping .

JOURNAL OF LUMINESCENCE, 2009, 129 (01) :50-54

[44] Manganese-activated luminescence in ZnGa2O4 [J].

Yu, CF ;

Lin, P .

JOURNAL OF APPLIED PHYSICS, 1996, 79 (09) :7191-7197

[45] Molten salt synthesis of magnesium aluminate (MgAl2O4) spinel powder [J].

Zhang, SW ;

Jayaseelan, DD ;

Bhattacharya, G ;

Lee, WE .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (05) :1724-1726

[46] The different luminescent characteristics of MgAl2O4:Mn2+ between phosphor powder and nanoparticles [J].

Zhong, Ruixia ;

Zhang, Jiahua ;

Wei, Hanzhi ;

Qi, Xiwei ;

Li, Mingya ;

Han, Xiumei .

CHEMICAL PHYSICS LETTERS, 2011, 508 (4-6) :207-209

[47]

Zou H., 2013, Adv. Mater. Res., V815, P662, DOI [10.4028/www.scientific.net/AMR.815.662, DOI 10.4028/WWW.SCIENTIFIC.NET/AMR.815.662]

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