A Decade of Electrocatalysis with Metal Aerogels: A Perspective

被引:19
作者
Li, Weishan [1 ]
Weng, Beibei [1 ]
Sun, Xiaoyue [1 ]
Cai, Bin [2 ]
Huebner, Rene [3 ]
Luo, Yunjun [1 ]
Du, Ran [1 ]
机构
[1] Beijing Inst Technol, Minist Educ, Sch Mat Sci & Engn, Key Lab High Energy Dens Mat, Beijing 100081, Peoples R China
[2] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
[3] Helmholtz Zent Dresden Rossendorf, Inst Ion Beam Phys & Mat Res, Bautzner Landstr 400, D-01328 Dresden, Germany
基金
中国国家自然科学基金;
关键词
electrocatalysis; metal aerogels; sol-gel; nanostructures; porous materials; HIGH-PERFORMANCE ELECTROCATALYST; BIMETALLIC AEROGELS; OXIDATION REACTION; EVOLUTION REACTION; BUILDING-BLOCKS; CU AEROGEL; PD; AG; NANOPARTICLES; AU;
D O I
10.3390/catal13010167
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nowadays, great efforts have been spent on addressing concerns over energy and environmental crises. Among these efforts, electrocatalysis is widely recognized and studied for its high efficiency and easy processability. As a class of emerging electrocatalysts, metal aerogels (MAs) stand out in the last decade. In virtue of their three-dimensional conductive pathways, their library of catalytically/optically active sites, and their robust network structures, MAs have unique advantages in electrocatalysis. However, due to the short history of MAs, there is insufficient research on them, leaving significant room for material design and performance optimization. This perspective will mainly focus on electrocatalysis with MAs, aiming to summarize the state-of-the-art progress and to guide the on-target design of efficient MAs-based electrocatalysts towards energy- and environment-related applications.
引用
收藏
页数:18
相关论文
共 100 条
[1]   Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007) [J].
Aleman, J. ;
Chadwick, A. V. ;
He, J. ;
Hess, M. ;
Horie, K. ;
Jones, R. G. ;
Kratochvil, P. ;
Meisel, I. ;
Mita, I. ;
Moad, G. ;
Penczek, S. ;
Stepto, R. F. T. .
PURE AND APPLIED CHEMISTRY, 2007, 79 (10) :1801-1827
[2]   Hydrogels and Aerogels from Noble Metal Nanoparticles [J].
Bigall, Nadja C. ;
Herrmann, Anne-Kristin ;
Vogel, Maria ;
Rose, Marcus ;
Simon, Paul ;
Carrillo-Cabrera, Wilder ;
Dorfs, Dirk ;
Kaskel, Stefan ;
Gaponik, Nikolai ;
Eychmueller, Alexander .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (51) :9731-9734
[3]   Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels [J].
Birdja, Yuvraj Y. ;
Perez-Gallent, Elena ;
Figueiredo, Marta C. ;
Gottle, Adrien J. ;
Calle-Vallejo, Federico ;
Koper, Marc T. M. .
NATURE ENERGY, 2019, 4 (09) :732-745
[4]   Direct solution-based reduction synthesis of Au, Pd, and Pt aerogels [J].
Burpo, Fred J. ;
Nagelli, Enoch A. ;
Morris, Lauren A. ;
McClure, Joshua P. ;
Ryu, Madeline Y. ;
Palmer, Jesse L. .
JOURNAL OF MATERIALS RESEARCH, 2017, 32 (22) :4153-4165
[5]   Promoting Electrocatalysis upon Aerogels [J].
Cai, Bin ;
Eychmueller, Alexander .
ADVANCED MATERIALS, 2019, 31 (31)
[6]   Core-Shell Structuring of Pure Metallic Aerogels towards Highly Efficient Platinum Utilization for the Oxygen Reduction Reaction [J].
Cai, Bin ;
Huebner, Rene ;
Sasaki, Kotaro ;
Zhang, Yuanzhe ;
Su, Dong ;
Ziegler, Christoph ;
Vukmirovic, Miomir B. ;
Rellinghaus, Bernd ;
Adzic, Radoslav R. ;
Eychmueller, Alexander .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (11) :2963-2966
[7]   Multimetallic Hierarchical Aerogels: Shape Engineering of the Building Blocks for Efficient Electrocatalysis [J].
Cai, Bin ;
Dianat, Arezoo ;
Huebner, Rene ;
Liu, Wei ;
Wen, Dan ;
Benad, Albrecht ;
Sonntag, Luisa ;
Gemming, Thomas ;
Cuniberti, Gianaurelio ;
Eychmueller, Alexander .
ADVANCED MATERIALS, 2017, 29 (11)
[8]   Function-Led Design of Aerogels: Self-Assembly of Alloyed PdNi Hollow Nanospheres for Efficient Electrocatalysis [J].
Cai, Bin ;
Wen, Dan ;
Liu, Wei ;
Herrmann, Anne-Kristin ;
Benad, Albrecht ;
Eychmueller, Alexander .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (44) :13101-13105
[9]   Hydrogen oxidation reaction in alkaline media: From mechanism to recent electrocatalysts [J].
Cong, Yuanyuan ;
Yi, Baolian ;
Song, Yujiang .
NANO ENERGY, 2018, 44 :288-303
[10]   Controlled organization of building blocks to prepare three-dimensional architecture of Pd-Ag aerogel as a high active electrocatalyst toward formic acid oxidation [J].
Douk, Abdollatif Shafaei ;
Saravani, Hamideh ;
Abad, Mehdi Zareie Yazdan ;
Noroozifar, Meissam .
COMPOSITES PART B-ENGINEERING, 2019, 172 :309-315