Rational Design of Transition Metal Phosphide-Based Electrocatalysts for Hydrogen Evolution

被引：207

作者：

Liu, Dong ^{[1
,2
]}

Xu, Guangyu ^{[1
]}

Yang, Huan ^{[3
]}

Wang, Haitao ^{[1
]}

Xia, Bao Yu ^{[4
]}

机构：

[1] Wuhan Inst Technol, Novel Catalyt Mat Hubei Engn Res Ctr, Sch Chem & Environm Engn, Hubei Key Lab Novel Reactor & Green Chem Technol E, Wuhan 430205, Hubei, Peoples R China

[2] Beijing Technol & Business Univ, China Natl Light Ind Council, Key Lab Proc, Qual Evaluat Technol Green Plast, Beijing 100048, Peoples R China

[3] Wuhan Inst Technol, Sch Mat Sci & Engn, Hubei Key Lab Plasma Chem & Adv Mat, Wuhan 430205, Hubei, Peoples R China

[4] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Key Lab Mat Chem Energy Convers & Storage, Minist Educ Hubei Key Lab Mat Chem & Serv Failure, Wuhan 430074, Hubei, Peoples R China

来源：

ADVANCED FUNCTIONAL MATERIALS | 2023年 / 33卷 / 07期

基金：

中国国家自然科学基金;

关键词：

electrocatalysts; electrocatalytic activity; hydrogen evolution; structure engineering; transition metal phosphides; EFFICIENT ELECTROCATALYST; TUNGSTEN PHOSPHIDE; NICKEL PHOSPHIDE; NANOSHEETS; PERFORMANCE; CATALYSTS; NITRIDE; SURFACE; FEP; PH;

D O I：

10.1002/adfm.202208358

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Developing efficient and inexpensive electrocatalysts for the hydrogen evolution reaction (HER) is critical to the commercial viability of electrochemical clean energy technologies. Transition metal phosphides (TMPs), with the merits of abundant reserves, unique structure, tunable composition, and high electronic conductivity, are recognized as attractive HER catalytic materials. Nevertheless, the HER electrocatalytic activity of TMPs is still limited by various thorough issues and inherent performance bottlenecks. In this review, these issues are carefully sorted, and the corresponding reasonable explanations and solutions are elucidated on the basis of the HER catalytic activity origins of TMPs. Subsequently, highly targeted multiscale strategies to improve the HER performance of TMPs are comprehensively presented. Additionally, critical scientific issues for constructing high-efficiency TMP-based electrocatalysts are proposed. Finally, the HER reaction process, catalytic mechanism research, TMP-based catalyst construction, and their application expansion are mentioned as challenges and future directions for this research field. Expectedly, this review offers professional and targeted guidelines for the rational design and practical application of TMP-based HER catalysts.

引用

页数：19

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