Advance on nickel- and palladium-catalyzed insertion copolymerization of ethylene and acrylate monomers

被引：21

作者：

Zheng, Handou ^{[1
]}

Qiu, Zonglin ^{[1
]}

Li, Donghui ^{[1
]}

Pei, Lixia ^{[2
,3
]}

Gao, Haiyang ^{[1
,4
]}

机构：

[1] Sun Yat sen Univ, Sch Mat Sci & Engn, PCFM Lab, GD HPPC Lab, Guangzhou, Peoples R China

[2] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou, Peoples R China

[3] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Peoples R China

[4] Sun Yat sen Univ, Sch Mat Sci & Engn, PCFM Lab, GD HPPC Lab, Guangzhou 510275, Peoples R China

来源：

JOURNAL OF POLYMER SCIENCE | 2023年 / 61卷 / 23期

基金：

中国国家自然科学基金;

关键词：

acrylate monomers; copolymer; copolymerization; ethylene; nickel and palladium catalysts; ALPHA-DIIMINE-NICKEL; PHOSPHINE-SULFONATE PALLADIUM; OLEFIN POLYMERIZATION; LIVING POLYMERIZATION; METHYL ACRYLATE; POLAR MONOMER; EFFICIENT INCORPORATION; ALKYL COMPLEXES; VINYL MONOMERS; LIGAND;

D O I：

10.1002/pol.20230389

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Nickel- and palladium-catalyzed insertion copolymerization of ethylene and acrylate comonomers for synthesis of ethylene-acrylates copolymers have attracted much academic and industrial interests and remained highly challenging. This review provides an overview of the developments in nickel- and palladium-catalyzed insertion copolymerization of ethylene and acrylate comonomers. Mechanistic interpretation of metal-catalyzed insertion copolymerization of ethylene and acrylate comonomers is described. Late transition metal catalysts are divided to nickel-based and palladium-based catalysts with different chelate ligands. The effects of catalyst structure on copolymerization performance and copolymer microstructure are comprehensively discussed. This review aims to promote the design and development of nickel and palladium catalysts for ethylene/acrylate copolymerizations and synthesis of ethylene-acrylates copolymers.

引用

页码：2987 / 3021

页数：35

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