Advance on nickel- and palladium-catalyzed insertion copolymerization of ethylene and acrylate monomers

被引：21
作者：
Zheng, Handou [1 ]
Qiu, Zonglin [1 ]
Li, Donghui [1 ]
Pei, Lixia [2 ,3 ]
Gao, Haiyang [1 ,4 ]
机构：
[1] Sun Yat sen Univ, Sch Mat Sci & Engn, PCFM Lab, GD HPPC Lab, Guangzhou, Peoples R China
[2] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou, Peoples R China
[3] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Peoples R China
[4] Sun Yat sen Univ, Sch Mat Sci & Engn, PCFM Lab, GD HPPC Lab, Guangzhou 510275, Peoples R China
来源：
JOURNAL OF POLYMER SCIENCE | 2023年 / 61卷 / 23期
基金：
中国国家自然科学基金;
关键词：
acrylate monomers; copolymer; copolymerization; ethylene; nickel and palladium catalysts; ALPHA-DIIMINE-NICKEL; PHOSPHINE-SULFONATE PALLADIUM; OLEFIN POLYMERIZATION; LIVING POLYMERIZATION; METHYL ACRYLATE; POLAR MONOMER; EFFICIENT INCORPORATION; ALKYL COMPLEXES; VINYL MONOMERS; LIGAND;
D O I：
10.1002/pol.20230389
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Nickel- and palladium-catalyzed insertion copolymerization of ethylene and acrylate comonomers for synthesis of ethylene-acrylates copolymers have attracted much academic and industrial interests and remained highly challenging. This review provides an overview of the developments in nickel- and palladium-catalyzed insertion copolymerization of ethylene and acrylate comonomers. Mechanistic interpretation of metal-catalyzed insertion copolymerization of ethylene and acrylate comonomers is described. Late transition metal catalysts are divided to nickel-based and palladium-based catalysts with different chelate ligands. The effects of catalyst structure on copolymerization performance and copolymer microstructure are comprehensively discussed. This review aims to promote the design and development of nickel and palladium catalysts for ethylene/acrylate copolymerizations and synthesis of ethylene-acrylates copolymers.
引用
收藏
页码：2987 / 3021
页数：35
相关论文
共 50 条
[21]   A "Catalyst plus Support" Strategy for Salicylaldimine Nickel Catalyzed Ethylene Polymerization and Copolymerization with Polar Monomers [J].
Wang, Zihao ;
Yang, Lei ;
Xu, Mengli ;
Tan, Chen ;
Chen, Changle .
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2023, 39 (05) :726-730
[22]   Copolymerization of ethylene with polar styrene monomers catalyzed by phosphino-dihydronaphtholate neutral nickel catalysts [J].
Wang, Fei ;
Wang, Xu-ling ;
Pan, Li ;
Mao, Xiao-hui ;
Wu, Hao-yang ;
Li, Yue-sheng .
JOURNAL OF POLYMER SCIENCE, 2024, 62 (10) :2058-2070
[23]   Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using "Sandwich" Diimine Palladium Catalysts [J].
Allen, Kate E. ;
Campos, Jesus ;
Daugulis, Olafs ;
Brookhart, Maurice .
ACS CATALYSIS, 2015, 5 (01) :456-464
[24]   Palladium-Catalyzed Homo- and Copolymerization of Polar Monomers: Synthesis of Aliphatic and Aromatic Polymers [J].
Ito, Shingo .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2018, 91 (02) :251-261
[25]   Ortho-Phosphinobenzenesulfonate: A Superb Ligand for Palladium-Catalyzed Coordination-Insertion Copolymerization of Polar Vinyl Monomers [J].
Nakamura, Akifumi ;
Anselment, Timo M. J. ;
Claverie, Jerome ;
Goodall, Brian ;
Jordan, Richard F. ;
Mecking, Stefan ;
Rieger, Bernhard ;
Sen, Ayusman ;
Van Leeuwen, Piet W. N. M. ;
Nozaki, Kyoko .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (07) :1438-1449
[26]   Ni/Pd-catalyzed coordination-insertion copolymerization of ethylene with alkyl acrylate [J].
Baruah, Urmilla ;
Saikia, Prakash J. ;
Baruah, Shashi D. .
POLYMER BULLETIN, 2020, 77 (11) :6105-6134
[27]   Crystalline Isotactic Polar Polypropylene from the Palladium-Catalyzed Copolymerization of Propylene and Polar Monomers [J].
Ota, Yusuke ;
Ito, Shingo ;
Kobayashi, Minoru ;
Kitade, Shinichi ;
Sakata, Kazuya ;
Tayano, Takao ;
Nozaki, Kyoko .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (26) :7505-7509
[28]   Palladium-Catalyzed Ethylene/Methyl Acrylate Cooligomerization: Effect of a New Nonsymmetric α-Diimine [J].
Meduri, Angelo ;
Montini, Tiziano ;
Ragaini, Fabio ;
Fornasiero, Paolo ;
Zangrando, Ennio ;
Milani, Barbara .
CHEMCATCHEM, 2013, 5 (05) :1170-1183
[29]   Photoresponsive Palladium and Nickel Catalysts for Ethylene Polymerization and Copolymerization [J].
Peng, Dan ;
Chen, Changle .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (41) :22195-22200
[30]   Effect of excess halide on the palladium-catalyzed insertion-triggered radical copolymerization of methyl acrylate and 1-hexene [J].
Albeniz, Ana C. ;
Espinet, Pablo ;
Lopez-Fernandez, Raquel .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (19) :5682-5691
12345