A closer inspection of the structural, mechanical, optical and radiation shielding properties of GeO2-doped magnesium-telluroborate glasses

被引:31
|
作者
Shaaban, Khamis S. S. [1 ]
Basha, Beriham [2 ]
Alrowaili, Ziad A. A. [3 ]
Al-Buriahi, Mohammad S. S. [4 ]
Abdel Wahab, Essam A. A. [5 ]
机构
[1] Al Azhar Univ, Fac Sci, Dept Chem, POB 71524, Assiut, Egypt
[2] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Phys, POB 84428, Riyadh 11671, Saudi Arabia
[3] Jouf Univ, Coll Sci, Phys Dept, POB 2014, Sakaka, Saudi Arabia
[4] Sakarya Univ, Dept Phys, Sakarya, Turkiye
[5] Al Azhar Univ, Fac Sci, Dept Phys, POB 71524, Assiut, Egypt
关键词
mechanical; optical; shielding; structural; telluroborate glasses; REFRACTIVE-INDEX; MODEL;
D O I
10.1515/ract-2023-0140
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
GeO2-doped magnesium-telluroborate transparent glasses were synthesized in the current investigation using the traditional melt-quench procedure. XRD and FT-IR were used to examine the glasses' structural properties. Following the measurement of the density, various physical parameters (including oxygen molar volume, oxygen packing density, etc.) were estimated and examined. From the FTIR results, one can deduce that clear structural alterations are seen which support the presence and conversion of BO3 and BO4 units. This is a result of the glass network forming more GeO4, TeO4, and BO4 units, which means that decreased NBO is forming, and more stiff networks are forming as a result. The increase in the overall stretching force constant of the glasses may also have an impact on the elastic moduli. The optical parameters were studied as optical energy band gap, Urbach energy and refractive index of the fabricated glass. According to the HVL data, the current glasses have a significant ability to lessen the intensity of gamma rays with lower energy. The glass with a small amount of GeO2 has a high HVL, whereas the glass with a higher amount of GeO2 has a lower HVL, as shown by the HVL data. The G5 glass demonstrated its superiority as a shielding glass over the other glass samples (G1-G4).
引用
收藏
页码:713 / 724
页数:12
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