Impact of a non-magnetic Sr2+ion doping on the magnetic and optical properties of Gd2-xSrxNiMnO6 (x=0,0.3,0.5) double perovskite

被引：2
作者：
Nazir, Nazima [1 ]
Ikram, Afreen [2 ]
Ikram, Mohd [1 ]
机构：
[1] Natl Inst Technol, Dept Phys, Srinagar 190006, India
[2] Natl Inst Technol, Met & Mat Engn Dept, Srinagar 190006, India
来源：
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | 2023年 / 571卷
关键词：
CURIE-TEMPERATURE; NANOSTRUCTURES;
D O I：
10.1016/j.jmmm.2023.170549
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The current study investigates the magnetization and optical characteristics of Sr-doped Gd2NiMnO6. Each sample's ZFC and FC magnetization measurements are presented. We discovered that the Curie temperature (TC) increases with doping. The ferromagnetic(FM) and antiferromagnetic(AFM) interactions cause different transitions in the pristine sample. The replacement of a non-magnetic Sr+2 ion reduces the Gd-Mn/Ni and Gd-Gd spin couplings, inhibiting AFM ordering and increasing the curie temperature for the doped sample in the low-temperature zone. Also decreased bandgap with doping was observed. Raman demonstrates two strong antisymmetric and symmetric modes, whereas FTIR shows two strong absorption bands caused by metal-oxygen stretching bands. Relying on the modified magnetic properties and also the calculated Eg values, the as-prepared samples might be used as a photocatalyst, and the reduction in bandgap owing to doping may find applications in solar cells.
引用
收藏
页数：8
相关论文
共 46 条
[1]   Synthesis and magnetic properties of LiFe5O8 powders by a sol-gel process [J].
An, SY ;
Shim, IB ;
Kim, CS .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2005, 290 :1551-1554
[2]   FERROMAGNETISM AND FERRIMAGNETISM OF OXYGEN SPINELS CONTAINING TETRAVALENT MANGANESE [J].
BLASSE, G .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1966, 27 (02) :383-&
[3]   An investigation of structural, magnetic and dielectric properties of R2NiMnO6 (R = rare earth, Y) [J].
Booth, R. J. ;
Fillman, R. ;
Whitaker, H. ;
Nag, Abanti ;
Tiwari, R. M. ;
Ramanujachary, K. V. ;
Gopalakrishnan, J. ;
Lofland, S. E. .
MATERIALS RESEARCH BULLETIN, 2009, 44 (07) :1559-1564
[4]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[5]   Multiple magnetic phases of La2CoMnO6-δ (0≤δ≤0.05) -: art. no. 014401 [J].
Dass, RI ;
Goodenough, JB .
PHYSICAL REVIEW B, 2003, 67 (01)
[6]   Nature of spiral state and absence of electric polarisation in Sr-doped YBaCuFeO5 revealed by first-principle study [J].
Dey, Dibyendu ;
Nandy, S. ;
Maitra, T. ;
Yadav, C. S. ;
Taraphder, A. .
SCIENTIFIC REPORTS, 2018, 8
[7]   Magnetism, hysteresis cycle, and Ir-substitution doping of Sr2CrIrO6 double perovskite: A Monte Carlo simulation [J].
El Rhazouani, O. ;
El Khatabi, M. ;
Zarhri, Z. ;
Slassi, A. ;
Benyoussef, A. ;
El Kenz, A. .
PHYSICS LETTERS A, 2016, 380 (48) :4075-4082
[8]   Humidity Sensors Principle, Mechanism, and Fabrication Technologies: A Comprehensive Review [J].
Farahani, Hamid ;
Wagiran, Rahman ;
Hamidon, Mohd Nizar .
SENSORS, 2014, 14 (05) :7881-7939
[9]   Understanding the structural, optical, and dielectric characteristics of SrLaLiTe1-xMnxO6 perovskites [J].
Halizan, M. Z. M. ;
Mohamed, Z. ;
Yahya, A. K. .
SCIENTIFIC REPORTS, 2021, 11 (01)
[10]   Enhancement of the magnetocaloric effect driven by changes in the crystal structure of Al- doped GGG, Gd3Ga5 -xAlxO12(0 ≤ x ≤ 5) [J].
Hamilton, A. C. Sackville ;
Lampronti, G. I. ;
Rowley, S. E. ;
Dutton, S. E. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2014, 26 (11)
12345