Selective Laser Sintering of Polydimethylsiloxane Composites

被引:12
作者
Wang, Jinzhi [1 ]
Sun, Shaojie [1 ]
Li, Xue [1 ]
Fei, Guoxia [1 ]
Wang, Zhanhua [1 ]
Xia, Hesheng [1 ]
机构
[1] Sichuan Univ, Polymer Res Inst, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China
关键词
silicone powder; carbon nanotubes; laser sintering; self-healing; STRAIN SENSORS; POLYMER NANOCOMPOSITES; POWDER; POLYURETHANE; SCAFFOLD;
D O I
10.1089/3dp.2021.0105
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Conductive silicone elastomer carbon nanotubes (CNTs) composites possess potential applications in a variety of fields, including electronic skin, wearable electronics, and human motion detection. Based on a novel self-made covalent adaptable network (CANs) of polydimethylsiloxane (PDMS) containg dynamic steric-hindrance pyrazole urea bond (PDMS-CANs), CNTs wrapped PDMS-CANs (CNTs@PDMS-CANs) powders were prepared by a liquid phase adsorption and deposition, and were successfully used for selective laser sintering (SLS) three-dimensional printing. SLS-printed PDMS-CANs/CNTs nanocomposites possess high electrical conductivity and low percolation threshold as SLS is one kind of quasi-static processing, which leads to the formation of conductive segregated CNTs network by using the PDMS powders with special CNTs wrapped structure. The introduction of dynamic pyrazole urea bond endows the materials self-healing capability under electrothermal and photothermal stimulus. In addition, due to the resistance difference of the damaged and intact areas, crack diagnosing can be realized by infrared thermograph under electricity. In an application demonstration in strain sensor, the composite exhibits a regular cyclic electrical resistance change at cyclic compression and bending, indicating a relative high reliability.
引用
收藏
页码:684 / 696
页数:13
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