Nacre-Inspired Bacterial Cellulose/Mica Nanopaper with Excellent Mechanical and Electrical Insulating Properties by Biosynthesis

被引:42
作者
Sun, Wen-Bin [1 ]
Han, Zi-Meng [1 ]
Yue, Xin [1 ]
Zhang, Hao-Yu [1 ]
Yang, Kun-Peng [1 ]
Liu, Zhao-Xiang [1 ]
Li, De-Han [1 ]
Zhao, Yu-Xiang [1 ]
Ling, Zhang-Chi [1 ]
Yang, Huai-Bin [1 ]
Guan, Qing-Fang [1 ]
Yu, Shu-Hong [1 ,2 ]
机构
[1] Univ Sci & Technol China, Hefei Natl Res Ctr Phys Sci Microscale, Div Nanomat & Chem, Anhui Engn Lab Biomimet Mat,Inst Biomimet Mat & Ch, Hefei 230026, Peoples R China
[2] Southern Univ Sci & Technol, Inst Innovat Mat, Dept Mat Sci & Engn, New Cornerstone Sci Lab,Dept Chem, Shenzhen 518055, Peoples R China
基金
中国国家自然科学基金;
关键词
biosynthesis; mechanical insulation properties; nacre-inspired materials; nanopaper; electrical insulating properties; SPACE; TOUGH;
D O I
10.1002/adma.202300241
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The exploration of extreme environments has become necessary for understanding and changing nature. However, the development of functional materials suitable for extreme conditions is still insufficient. Herein, a kind of nacre-inspired bacterial cellulose (BC)/synthetic mica (S-Mica) nanopaper with excellent mechanical and electrical insulating properties that has excellent tolerance to extreme conditions is reported. Benefited from the nacre-inspired structure and the 3D network of BC, the nanopaper exhibits excellent mechanical properties, including high tensile strength (375 MPa), outstanding foldability, and bending fatigue resistance. In addition, S-Mica arranged in layers endows the nanopaper with remarkable dielectric strength (145.7 kV mm(-1)) and ultralong corona resistance life. Moreover, the nanopaper is highly resistant to alternating high and low temperatures, UV light, and atomic oxygen, making it an ideal candidate for extreme environment-resistant materials.
引用
收藏
页数:9
相关论文
共 39 条
  • [1] Baranov A.I., 2003, Ferroelectrics, Vol, V286, pag, P141
  • [2] Bouville F, 2014, NAT MATER, V13, P508, DOI [10.1038/NMAT3915, 10.1038/nmat3915]
  • [3] Chen, 2022, ADV FUNCT MATER, V33
  • [4] DIELECTRIC BREAKDOWN IN THIN MICA CRYSTALS
    DAVIDSON, AT
    YOFFE, AD
    [J]. NATURE, 1965, 206 (4990) : 1247 - &
  • [5] Preparation and characterization of thermally stable cellulose nanocrystals via a sustainable approach of FeCl3-catalyzed formic acid hydrolysis
    Du, Haishun
    Liu, Chao
    Mu, Xindong
    Gong, Wenbo
    Lv, Dong
    Hong, Yimei
    Si, Chuanling
    Li, Bin
    [J]. CELLULOSE, 2016, 23 (04) : 2389 - 2407
  • [6] Challenges and Opportunities of Self-Healing Polymers and Devices for Extreme and Hostile Environments
    Ekeocha, James
    Ellingford, Christopher
    Pan, Min
    Wemyss, Alan M.
    Bowen, Christopher
    Wan, Chaoying
    [J]. ADVANCED MATERIALS, 2021, 33 (33)
  • [7] Bark-mimetic layer-by-layer assembled montmorillonite/poly(p-aminostyrene) flexible nanocomposites shielding atomic oxygen erosion
    Gao, Min
    Liu, Bing-jun
    Gao, Long-cheng
    Yin, Peng-gang
    Jiang, Lei
    [J]. CHINESE JOURNAL OF POLYMER SCIENCE, 2013, 31 (01) : 83 - 87
  • [8] Materials for space exploration and settlement
    Ghidini, Tommaso
    [J]. NATURE MATERIALS, 2018, 17 (10) : 846 - 850
  • [9] Advances in Polyimide-Based Materials for Space Applications
    Gouzman, Irina
    Grossman, Eitan
    Verker, Ronen
    Atar, Nurit
    Bolker, Asaf
    Eliaz, Noam
    [J]. ADVANCED MATERIALS, 2019, 31 (18)
  • [10] GUAN QF, 2021, NANO LETT, V31