Recent Advances in Nonprecious Metal Catalysis

被引：22

作者：

Haibach, Michael C. ^{[1
]}

Shekhar, Shashank ^{[1
]}

Ahmed, Tonia S. ^{[1
]}

Ickes, Andrew R. ^{[1
]}

机构：

[1] AbbVie Inc, Proc Res & Dev, N Chicago, IL 60064 USA

来源：

ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2023年 / 27卷 / 03期

关键词：

nonprecious metals; catalysis; nickel; copper; iron; cobalt; manganese; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC HYDROGENATION; FACILE ACCESS; ALKYNES; HYDROAMINATION; OLEFINS; 1,3-DIENES; ALCOHOLS; ESTERS;

D O I：

10.1021/acs.oprd.2c00344

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Nonprecious-metal-catalyzed alternatives to powerful precious metal transformations are of increasing interest in academia and the pharmaceutical industry due to the lower cost, better sustainability, and lower toxicity. With the continual growth in the broad field of nonprecious metal catalysis (NPMC), we have chosen to highlight selected articles published from March to June 2022 which are intended to highlight examples of NPMC that we feel may be especially relevant to pharmaceutical development. We aim to inspire academic and industrial innovation in NPMC through the discussion herein.

引用

页码：423 / 447

页数：25

共 90 条

[61] Cobalt-Catalyzed Carbo- and Hydrocyanation of Alkynes via C-CN Bond Activation [J].

Wang, Chang-Sheng ;

Yu, Yongqi ;

Sunada, Yusuke ;

Wang, Chen ;

Yoshikai, Naohiko .

ACS CATALYSIS, 2022, 12 (07) :4054-4066

[62] Three-component carboacylation of alkenes via cooperative nickelaphotoredox catalysis [J].

Wang, Dingyi ;

Ackermann, Lutz .

CHEMICAL SCIENCE, 2022, 13 (24) :7256-7263

[63] Modular and Facile Access to Chiral α-Aryl Phosphates via Dual Nickel- and Photoredox-Catalyzed Reductive Cross-Coupling [J].

Wang, Hepan ;

Zheng, Purui ;

Wu, Xiaoqiang ;

Li, Yuqiang ;

Xu, Tao .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (09) :3989-3997

[64] N-Heterocyclic Carbene-Nickel-Catalyzed Regioselective Diarylation of Aliphatic-1,3-Dienes [J].

Wang, Hongyu ;

Liu, Chen-Fei ;

Tan, Tong-De ;

Khoo, Kyna Ru Bin ;

Koh, Ming Joo .

ACS CATALYSIS, 2022, 12 (01) :724-732

[65] Nickel-Catalyzed Arylative Carboxylation of Alkynes with Arylmagnesium Reagents and Carbon Dioxide Leading to Trisubstituted Acrylic Acids [J].

Wang, Sheng ;

Xi, Chanjuan .

ORGANIC LETTERS, 2018, 20 (13) :4131-4134

[66] Access to 4-Trifluoromethyl Quinolines via Cu-Catalyzed AnnulationReaction of Ketone Oxime Acetates withortho-TrifluoroacetylAnilines under Redox-Neutral Conditions [J].

Wang, Zhen-Hua ;

Shen, Li-Wen ;

Yang, Ping ;

You, Yong ;

Zhao, Jian-Qiang ;

Yuan, Wei-Cheng .

JOURNAL OF ORGANIC CHEMISTRY, 2022, 87 (09) :5804-5816

[67] Three-Component Coupling of Arenes, Ethylene, and Alkynes Catalyzed by a Cationic Bis(phosphine) Cobalt Complex: Intercepting Metallacyclopentenes for C-H Functionalization [J].

Whitehurst, William G. ;

Kim, Junho ;

Koenig, Stefan G. ;

Chirik, Paul J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (10) :4530-4540

[68] Enantioselective Synthesis of Secondary β-Trifluoromethyl Alcoholsvia Catalytic Asymmetric Reductive Trifluoroalkylation and Diastereoselective Reduction [J].

Wu, Bing-Bing ;

Xu, Jie ;

Bian, Kang-Jie ;

Gao, Qian ;

Wang, Xi-Sheng .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (14) :6543-6550

[69] Nickel-Catalyzed Cross-Coupling of Acyl Chloride with Racemic α-Trifluoromethyl Bromide to Access Chiral α-Trifluoromethyl Ketones [J].

Wu, Juanjuan ;

Wu, Hongli ;

Liu, Xinyu ;

Zhang, Yuekun ;

Huang, Genping ;

Zhang, Chun .

ORGANIC LETTERS, 2022, 24 (24) :4322-4327

[70] Nickel-Catalyzed Three-Component Alkylacylation of Alkenes Enabled by a Photoactive Electron Donor-Acceptor Complex [J].

Xi, Xiaoxiang ;

Chen, Yukun ;

Yuan, Weiming .

ORGANIC LETTERS, 2022, 24 (22) :3938-3943

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