Recent Advances in Nonprecious Metal Catalysis

被引:22
作者
Haibach, Michael C. [1 ]
Shekhar, Shashank [1 ]
Ahmed, Tonia S. [1 ]
Ickes, Andrew R. [1 ]
机构
[1] AbbVie Inc, Proc Res & Dev, N Chicago, IL 60064 USA
关键词
nonprecious metals; catalysis; nickel; copper; iron; cobalt; manganese; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC HYDROGENATION; FACILE ACCESS; ALKYNES; HYDROAMINATION; OLEFINS; 1,3-DIENES; ALCOHOLS; ESTERS;
D O I
10.1021/acs.oprd.2c00344
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Nonprecious-metal-catalyzed alternatives to powerful precious metal transformations are of increasing interest in academia and the pharmaceutical industry due to the lower cost, better sustainability, and lower toxicity. With the continual growth in the broad field of nonprecious metal catalysis (NPMC), we have chosen to highlight selected articles published from March to June 2022 which are intended to highlight examples of NPMC that we feel may be especially relevant to pharmaceutical development. We aim to inspire academic and industrial innovation in NPMC through the discussion herein.
引用
收藏
页码:423 / 447
页数:25
相关论文
共 90 条
[1]   Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates [J].
Alfaro, Ricardo ;
Parra, Alejandro ;
Aleman, Jose ;
Garcia Ruano, Jose Luis ;
Tortosa, Mariola .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (37) :15165-15168
[2]   Sustainable preparation of photoactive indole-fused tetracyclic molecules: a new class of organophotocatalysts [J].
Bae, Jaehan ;
Iqbal, Naeem ;
Hwang, Ho Seong ;
Cho, Eun Jin .
GREEN CHEMISTRY, 2022, 24 (10) :3985-3992
[3]   Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids [J].
Bandar, Jeffrey S. ;
Ascic, Erhad ;
Buchwald, Stephen L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (18) :5821-5824
[4]   Where Does the Fluorine Come From? A Review on the Challenges Associated with the Synthesis of Organofluorine Compounds [J].
Caron, Stephane .
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2020, 24 (04) :470-480
[5]   Enantio- and Diastereoselective Copper-Catalyzed Allylboration of Alkynes with Allylic gem-Dichlorides [J].
Chaves-Pouso, Andrea ;
Alvarez-Constantino, Andres M. ;
Fananas-Mastral, Martin .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (23)
[6]   A Unified Approach to Decarboxylative Halogenation of (Hetero)aryl Carboxylic Acids [J].
Chen, Tiffany Q. ;
Pedersen, P. Scott ;
Dow, Nathan W. ;
Fayad, Remi ;
Hauke, Cory E. ;
Rosko, Michael C. ;
Danilov, Evgeny O. ;
Blakemore, David C. ;
Dechert-Schmitt, Anne-Marie ;
Knauber, Thomas ;
Castellano, Felix N. ;
MacMillan, David W. C. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (18) :8296-8305
[7]   Enantioselective Nickel-Catalyzed Reductive Aryl/Alkenyl-CyanoCyclization Coupling to All-Carbon Quaternary Stereocenters [J].
Chen, Zi-Hao ;
Sun, Rui-Ze ;
Yao, Fei ;
Hu, Xu-Dong ;
Xiang, Long-Xue ;
Cong, Hengjiang ;
Liu, Wen-Bo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (11) :4776-4782
[8]   Kinetic chiral resolutions of 1,2-diols and desymmetrization of glycerol catalyzed by glycerol kinase [J].
Chenault, HK ;
Chafin, LF ;
Liehr, S .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (12) :4039-4045
[9]   Catalytic Asymmetric Reductive Acyl Cross-Coupling: Synthesis of Enantioenriched Acyclic α,α-Disubstituted Ketones [J].
Cherney, Alan H. ;
Kadunce, Nathaniel T. ;
Reisman, Sarah E. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (20) :7442-7445
[10]   Photoinduced, Copper-Catalyzed Enantioconvergent Alkylations of Anilines by Racemic Tertiary Electrophiles: Synthesis and Mechanism [J].
Cho, Hyungdo ;
Suematsu, Hidehiro ;
Oyala, Paul H. ;
Peters, Jonas C. ;
Fu, Gregory C. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (10) :4550-4558