Converting Styrofoam Waste into Fuel Using a Sequential Pyrolysis Reactor and Natural Zeolite Catalytic Reformer

被引:1
作者
Suhartono [1 ]
Romli, Ate [1 ]
Prabowo, Bambang Hari [1 ]
Kusumo, Priyono [2 ]
Suharto [3 ]
机构
[1] Univ Jenderal Achmad Yani, Dept Chem Engn, Cimahi 40533, Indonesia
[2] Univ 17 Agustus 1945, Dept Chem Engn, Semarang 50233, Indonesia
[3] Natl Res & Innovat Agcy, Res Ctr Min Technol, Jakarta 35361, Lampung, Indonesia
关键词
Catalytic; Fuel; Natural-zeolite; Pyrolysis; Styrofoam; PLASTIC WASTE; OIL; CO;
D O I
10.14716/ijtech.v14i1.4907
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Converting 185tyrofoam plastic waste (SPW) into liquid pyrolysis oil (PLO) using a sequential pyrolysis reactor and natural zeolite catalytic vessel was conducted at relatively low temperatures from 160 degrees C to 260 degrees C and complete pyrolysis time, t(p) of 60-120 minutes. The presence of natural zeolites on a reformer vessel was intended to undergo the second stage degradation of pyrolysis gas produced without further heating. This work aims to find the yield and quality of PLO that are significantly influenced by the feedstocks of SPW and natural zeolite as a catalyst. The modification of zeolite enhances its fundamental characteristics and its effect on thermochemical behavior and pyrolysis reactions. Utilizing natural zeolite catalysts as TA-ZN (thermal activation) and AA-NZ (acid activation) increases the yield and quality of PLO as fuel. The utilization of the AA-NZ catalyst provided the highest PLO yield, lowest wax, and smallest solid deposit in the shortest at complete pyrolysis time, t(p). PLO produced from SPW pyrolysis with AA-NZ catalyst contains a higher range of hydrocarbon gasoline (C-5-C-12) as styrene, ethylbenzene, and methylbenzene with styrene compound as the highest amount of 74.63% and without a heavy hydrocarbon compound fraction (>C-20). According to the analysis of all physical properties and GC-MS characterization, this PLO lies within a range comparable to that of conventional commercial kerosene.
引用
收藏
页码:185 / 194
页数:10
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