ZnO/ZnFe2O4/zeolite composite catalyst for peroxymonosulfate oxidation and photocatalysis

被引:9
作者
Hu, Tianyu [1 ,2 ]
Li, Jianjun [1 ,2 ]
Wang, Lei [1 ]
Wang, Hongyang [1 ]
Zhang, Zhanqun [1 ]
Jiang, Wenxu [1 ]
Xue, Changguo [1 ]
机构
[1] Anhui Univ Sci & Technol, Dept Mat Sci & Engn, Huainan 232001, Peoples R China
[2] Anhui Univ Sci & Technol, Inst Environm Friendly Mat & Occupat Hlth, Wuhu 241003, Peoples R China
关键词
ZnO; Zeolite nanocomposites; Advanced oxidation process; Photocatalysis; Magnetic separation; Zinc ferrite; FABRICATION;
D O I
10.1016/j.matlet.2022.133310
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Magnetic ZnO/ZnFe2O4/Zeolite (ZFZ) catalysts were prepared by a solvothermal-microwave method and used for advanced oxidation processes. Careful investigations indicate ZFZ has a core-shell structure with ZnO/ ZnFe2O4 nanoparticles covered on the surface of Na-A zeolite. The specific saturation magnetization of ZFZ is up to 15.276 emu/g, which is sufficient for efficient magnetic separation. Experiments on advanced oxidation degradation of Rhodamine B indicate that ZFZ have remarkable catalytic activity for peroxymonosulfate oxidation. The degradation rate increased more than 3 times under UV-light irradiation, suggesting that ZFZ has stronger photocatalysis. The highest decomposition rate could reach 98.55 %. And after 5 cycles, a 79.11 % degradation rate still remained.
引用
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页数:4
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