A New Zinc Salt Chemistry for Aqueous Zinc-Metal Batteries

被引：50

作者：

Du, Haoran ^{[1
,2
]}

Dong, Yanhao ^{[3
]}

Li, Qing-Jie ^{[4
]}

Zhao, Ruirui ^{[2
]}

Qi, Xiaoqun ^{[1
]}

Kan, Wang-Hay ^{[5
]}

Suo, Liumin ^{[6
]}

Qie, Long ^{[1
]}

Li, Ju ^{[4
,7
]}

Huang, Yunhui ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mold Technol, Wuhan 430074, Hubei, Peoples R China

[2] Tongji Univ, Inst New Energy Vehicles, Sch Mat Sci & Engn, Shanghai 201804, Peoples R China

[3] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China

[4] MIT, Dept Nucl Sci & Engn, Cambridge, MA 02139 USA

[5] Chinese Acad Sci, China Spallat Neutron Source, Dongguan 523890, Guangdong, Peoples R China

[6] Chinese Acad Sci, Inst Phys, Beijing Adv Innovat Ctr Mat Genome Engn, Key Lab Renewable Energy,Beijing Key Lab New Energ, Beijing 100190, Peoples R China

[7] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA

来源：

ADVANCED MATERIALS | 2023年 / 35卷 / 25期

基金：

中国国家自然科学基金;

关键词：

aqueous electrolytes; Zn protection; Zn salts; Zn-metal batteries; ELECTROLYTE; STRATEGIES;

D O I：

10.1002/adma.202210055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aqueous zinc-ion batteries (ZIBs) are promising energy storage solutions with low cost and superior safety, but they suffer from chemical and electrochemical degradations closely related to the electrolyte. Here, a new zinc salt design and a drop-in solution for long cycle-life aqueous ZIBs are reported. The salt Zn(BBI)(2) with a rationally designed anion group, N-(benzenesulfonyl)benzenesulfonamide (BBI-), has a special amphiphilic molecular structure, which combines the benefits of hydrophilic and hydrophobic groups to properly tune the solubility and interfacial condition. This new zinc salt does not contain fluorine and is synthesized via a high-yield and low-cost method. It is shown that 1 m Zn(BBI)(2) aqueous electrolyte with a widened cathodic stability window effectively stabilizes Zn metal/H2O interface, mitigates chemical and electrochemical degradations, and enables both symmetric and full cells using a zinc-metal electrode.

引用

页数：11

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