Highly Sensitive Fluorescence Detection of 2,4,6-Trinitrophenol Based on Hydrogen-Bonded Organic Framework

被引:1
|
作者
Zhang, Wei [1 ]
Shen, Penglei [1 ]
Zhang, Xin [1 ]
Chen, Faqiang [1 ]
Xu, Hui [1 ]
Xu, Shiqing [1 ]
机构
[1] China Jiliang Univ, Inst Optoelect Mat & Devices, Key Lab Rare Earth Optoelect Mat & Devices Zhejian, Collage Opt & Elect Technol, Hangzhou 310018, Peoples R China
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2023年 / 649卷 / 15期
关键词
hydrogen-bonded organic framework; 2; 4; 6-trinitrophenol; fluorescence sensing; LOD; DESIGN;
D O I
10.1002/zaac.202300084
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The highly sensitive detection of carcinogenic pollutant 2,4,6-trinitrophenol (PA) is of great significance for environmental protection and human health. Based on the organic building block 1,3,6,8-tetrakis (p-benzoic acid) pyrene (H(4)TBAPy), the porous nano-scale hydrogen-bonded organic framework material (PFC-1) was successfully synthesized. The large & pi;-& pi; conjugated structure makes it to show excellent fluorescence characteristics. PFC-1 showed excellent selective fluorescence detection for PA. PFC-1 exhibited significant quenching effect upon the addition of PA. The quenching efficiency Ksv of PFC-1 material for PA is 9.14x10(4) M-1 and the limit of detection (LOD) reaches 0.75 & mu;M. PFC-1 exhibits excellent fluorescence sensing performance for PA, which greatly expands the potential application of hydrogen-bonded organic framework materials in the field of fluorescence sensing.
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页数:5
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