Carbon dots integrated into nickel-cobalt hydroxide as superior electrode for supercapattery

被引:8
|
作者
Cui, Yangbo [1 ]
Han, Chong [1 ]
Si, Huizheng [1 ]
Liu, Kaiyu [1 ]
Liu, Hongtao [1 ]
Sang, Shangbin [1 ]
Wu, Qiumei [2 ]
机构
[1] Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Chem Power Sources, Changsha 410083, Peoples R China
[2] Cent South Univ, State Key Powder Met Lab, Changsha 410083, Peoples R China
关键词
Nickel hydroxide; Cathodic electrodeposition; Cobalt; Carbon dots; Supercapattery; ELECTROCHEMICAL PERFORMANCE; NI(OH)(2) NANOSHEETS; GRAPHENE OXIDE; NI; FABRICATION; HYBRID; FOAM; COMPOSITE; SHEETS;
D O I
10.1016/j.electacta.2023.142279
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Nickel hydroxide (Ni(OH)2) is one of the most valuable electrode materials for supercapacitors. Owing to the low stability and conductivity of Ni(OH)2 electrode, the preparation of a fast and high-stability Ni(OH)2 electrode is a significant challenge. Nickel hydroxide integrated with cobalt and carbon dots (CDs-Co/Ni(OH)2) as a high performance electrode has been prepared by cathodic electrodeposition for supercapattery in this work. Compared with unintegrated Ni(OH)2 electrode or carbon dots integrated Ni(OH)2 electrode, the introduction of Co greatly improves the stability of the Ni(OH)2 electrode, particularly at high current density. The as-obtained CDs-Co/Ni(OH)2 electrode presents a high specific capacitance of 338.6 mAh/g at 5 A/g and an extraordinary cycling stability with 1000 cycles even under a high current density of 40 A/g (retaining 84.6%). Besides, the CDs-Co/Ni(OH)2 electrode exhibits an energy density of 281.2 Wh/kg at a power density of 57.2 kW/kg. Such a glorious stable CDs-Co/Ni(OH)2 electrode may provide significant insight into future multifarious electronics and electrified vehicle applications.
引用
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页数:9
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