Progress in semiconductor materials for photocathodic protection: Design strategies and applications in marine corrosion protection

Metal protection of offshore equipment is very complicated owing to the complex marine environment. Photocathodic protection (PCP) is one of the popular research topics in marine metal protection. The protection efficiency of photoanode depends largely on the photoelectric properties of semiconductor materials, viz. the process of charge separation, charge migration, and light absorption. In this article, the enhancement strategies, photoelectrochemical properties, and electron transfer mechanisms of different composites for PCP were reviewed and highlighted. Some photoanodes with unusual and striking properties were emphasized. In addition, the outlooks and challenges of the application of PCP and the design of photoanodes materials are proposed.