Recent advances in polyoxometalates acid-catalyzed organic reactions

被引:66
作者
Liu, Yu-Feng [1 ]
Hu, Chang-Wen [2 ]
Yang, Guo-Ping [1 ]
机构
[1] East China Univ Technol, Jiangxi Prov Key Lab Synthet Chem, Jiangxi Key Lab Mass Spectrometry & Instrumentat, Nanchang 330013, Peoples R China
[2] Beijing Inst Technol, Sch Chem & Chem Engn, Beijing Key Lab Photoelect Electrophoton Convers M, Key Lab Cluster Sci,Minist Educ, Beijing 100081, Peoples R China
关键词
Polyoxometalates; Acid catalysis; C -c bond formation; C -n bond formation; C -o bond formation; Heterocyclic synthesis; Cyanosilylation and hydrolysis reactions; ONE-POT SYNTHESIS; IONIC LIQUID; HETEROGENEOUS CATALYST; 2,4,5-TRISUBSTITUTED IMIDAZOLES; COFE2O4; NANOPARTICLES; PHOSPHOMOLYBDIC ACID; CONVENIENT SYNTHESIS; RECYCLABLE CATALYST; EFFICIENT CATALYSTS; PRINS CONDENSATION;
D O I
10.1016/j.cclet.2022.108097
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polyoxometalates (POMs) have conducive properties such as controlled Bronsted and Lewis acidity, high thermal stability, nontoxic nature, tunable solubility, and less corrosiveness. POMs have been extensively applied in catalytic organic reactions and have an exciting prospect for industrial applications. This review summarized recent progress in the application of POMs as acid catalysts for various organic reactions in-cluding C -C bond formation, C -N bond formation, C -O bond formation, heterocyclic synthesis reactions, cyanosilylation and hydrolysis reactions. Various POMs catalysts including heteropoly acids (HPAs) and cationic functionalized HPAs with Bronsted acidity, HPAs supported on non-precious metal support with Bronsted acidity (or both Bronsted and Lewis acidity), transition metal substituted POMs with Lewis acid-ity were applied in above reactions. This review attempts to provide up-to-date information about POMs acid-catalyzed organic reactions and propose future prospects.(c) 2023 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
引用
收藏
页数:12
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