Recent advances in polyoxometalates acid-catalyzed organic reactions

被引：77

作者：

Liu, Yu-Feng ^{[1
]}

Hu, Chang-Wen ^{[2
]}

Yang, Guo-Ping ^{[1
]}

机构：

[1] East China Univ Technol, Jiangxi Prov Key Lab Synthet Chem, Jiangxi Key Lab Mass Spectrometry & Instrumentat, Nanchang 330013, Peoples R China

[2] Beijing Inst Technol, Sch Chem & Chem Engn, Beijing Key Lab Photoelect Electrophoton Convers M, Key Lab Cluster Sci,Minist Educ, Beijing 100081, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2023年 / 34卷 / 05期

关键词：

Polyoxometalates; Acid catalysis; C -c bond formation; C -n bond formation; C -o bond formation; Heterocyclic synthesis; Cyanosilylation and hydrolysis reactions; ONE-POT SYNTHESIS; IONIC LIQUID; HETEROGENEOUS CATALYST; 2,4,5-TRISUBSTITUTED IMIDAZOLES; COFE2O4; NANOPARTICLES; PHOSPHOMOLYBDIC ACID; CONVENIENT SYNTHESIS; RECYCLABLE CATALYST; EFFICIENT CATALYSTS; PRINS CONDENSATION;

D O I：

10.1016/j.cclet.2022.108097

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polyoxometalates (POMs) have conducive properties such as controlled Bronsted and Lewis acidity, high thermal stability, nontoxic nature, tunable solubility, and less corrosiveness. POMs have been extensively applied in catalytic organic reactions and have an exciting prospect for industrial applications. This review summarized recent progress in the application of POMs as acid catalysts for various organic reactions in-cluding C -C bond formation, C -N bond formation, C -O bond formation, heterocyclic synthesis reactions, cyanosilylation and hydrolysis reactions. Various POMs catalysts including heteropoly acids (HPAs) and cationic functionalized HPAs with Bronsted acidity, HPAs supported on non-precious metal support with Bronsted acidity (or both Bronsted and Lewis acidity), transition metal substituted POMs with Lewis acid-ity were applied in above reactions. This review attempts to provide up-to-date information about POMs acid-catalyzed organic reactions and propose future prospects.(c) 2023 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.

引用

页数：12

共 169 条

[1]

Abbaspour-Gilandeh E., 2016, RSC ADV, V6, p554 4 4

[2] Understanding reaction kinetics, deprotonation and solvation of bronsted acidic protons in heteropolyacid catalyzed synthesis of biorenewable alkyl levulinates [J].

Ahmad, Ejaz ;

Khan, Tuhin Suvra ;

Alam, Md. Imteyaz ;

Pant, K. K. ;

Haider, M. Ali .

CHEMICAL ENGINEERING JOURNAL, 2020, 400

[3] Heteropoly acid encapsulated into zeolite imidazolate framework (ZIF-67) cage as an efficient heterogeneous catalyst for Friedel-Crafts acylation [J].

Ammar, Muhammad ;

Jiang, Sai ;

Ji, Shengfu .

JOURNAL OF SOLID STATE CHEMISTRY, 2016, 233 :303-310

[4] Review: biologically active pyrazole derivatives [J].

Ansari, Anam ;

Ali, Abad ;

Asif, Mohd ;

Shamsuzzaman .

NEW JOURNAL OF CHEMISTRY, 2017, 41 (01) :16-41

[5] Convenient one pot synthesis of some novel derivatives of thiazolo[2,3-b]dihydropyrimidinone possessing 4-methylthiophenyl moiety and evaluation of their antibacterial and antifungal activities [J].

Ashok, Mithun ;

Holla, Bantwal Shivarama ;

Kumari, Nalilu Suchetha .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2007, 42 (03) :380-385

[6] An Efficient Phosphotungstic Acid Catalysed Synthesis of 4,5-Dioxopyrrolidines and Study of the Mechanistic Effect of the Solvent on the Reaction [J].

Basu, Soumyadip ;

Ghosh, Tanushree ;

Maity, Suvendu ;

Ghosh, Prasanta ;

Mukhopadhyay, Chhanda .

CHEMISTRYSELECT, 2019, 4 (19) :5763-5767

[7] Beyond olefins: new metathesis directions for synthesis [J].

Becker, Marc R. ;

Watson, Rebecca B. ;

Schindler, Corinna S. .

CHEMICAL SOCIETY REVIEWS, 2018, 47 (21) :7867-7881

[8] Recent advances in the preparation of levulinic esters from biomass-derived furanic and levulinic chemical platforms using heteropoly acid (HPA) catalysts [J].

Bhat, Navya Subray ;

Mal, Sib Sankar ;

Dutta, Saikat .

MOLECULAR CATALYSIS, 2021, 505

[9] The use of polyoxometalates in protein crystallography - An attempt to widen a well-known bottleneck [J].

Bijelic, Aleksandar ;

Rompel, Annette .

COORDINATION CHEMISTRY REVIEWS, 2015, 299 :22-38

[10] Recent advances in intramolecular C-O/C-N/C-S bond formation via C-H functionalization [J].

Borpatra, Paran J. ;

Deka, Bhaskar ;

Deb, Mohit L. ;

Baruah, Pranjal K. .

ORGANIC CHEMISTRY FRONTIERS, 2019, 6 (20) :3445-3489

← 1 2 3 4 5 6 7 8 9 10 →