Microplasma and quenching-induced Co doped NiMoO4 nanorods with oxygen vacancies for electrochemical determination of glucose in food and serum

In this paper, Co-doped NiMoO4 nanorods with oxygen vacancies are synthesized on carbon cloth (Co-NiMoO4 NRs/CC) via microplasma and quenching-induced method. Owing to the surface defects and metal ion doping, the electronic structure and surface properties of the catalyst are tuned. Cyclic voltammetry (CV) and amperometry are used to investigate the electrocatalytic behavior of the glucose sensor in an alkaline medium with sensitivities of 7411 and 3125 mu A L mmol- 1 cm-2 in the linear range 1.0 mu mol L-1 to 1.0 mmol L-1 and 1.0 mmol L-1 to 7.0 mmol L-1, respectively. The detection limit is 0.079 mu mol L-1 at S/N = 3. Moreover, the as-prepared catalyst electrode is also successfully used in real food and serum samples, with a recovery rate of 97.1%107.4%. The DFT calculations show that the Co site of the catalyst significantly influenced glucose sensing performance. This idea expands the application of quenching chemistry in electrochemical sensing.