A novel Eu3+-doped SrLaGaO4 red phosphor with high efficiency and color purity for WLED applications

被引:18
作者
Qiu, Yuefeng [1 ]
Cui, Ruirui [1 ]
Zhang, Jun [2 ]
Deng, Chaoyong [1 ,3 ]
机构
[1] Guizhou Univ, Coll Big Data & Informat Engn, Key Lab Funct Composite Mat Guizhou Prov, Guiyang 550025, Peoples R China
[2] Guizhou Univ Commerce, Coll Comp & Informat Engn, Guiyang 550014, Peoples R China
[3] Guizhou Univ, Sch Elect & Informat Engn, Guiyang 550005, Peoples R China
基金
中国国家自然科学基金;
关键词
Phosphor; Quantum yield; Color purity; SrLaGaO4; Eu3+; PHOTOLUMINESCENCE PROPERTIES; LUMINESCENCE PROPERTIES; THERMAL-STABILITY; ENERGY-TRANSFER; LIGHT; XPS; EMISSION; EU(III); SITE;
D O I
10.1016/j.jssc.2023.124265
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel red SrLaGaO4: Eu3+ phosphor was successfully synthesized by solid-phase sintering method. X-ray diffractometer characterization shows that the phosphor possesses a tetragonal phase with a space group of I4/ mmm. XPS spectroscopy characterized the chemical composition and the presence of trivalent europium in samples. Under 395 nm excitation, the emission spectra showed one strong peak at 618 nm subjected to electronic transition of 5D0 -> 7F2. The quantum yield of the SrLaGaO4: 0.3Eu3+ is 90.9%. At 423 K, the luminous intensity of SrLaGaO4: 0.3Eu3+ phosphor is 60.9% of the initial value. Besides, the chromaticity coordinates of SrLaGaO4: 0.3Eu3+ is (0.6467, 0.353) and the color purity is 99.56%. Finally, white LED with chromaticity coordinates of (0.36, 0.37) was prepared by mixing sample with commercial green/blue phosphors. In conclusion, SrLaGaO4: Eu3+ phosphor is a very promising light-emitting material for WLED devices.
引用
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页数:10
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