Rapidly In Situ Cross-Linked Poly(butylene oxide) Electrolyte Interface Enabling Halide-Based All-Solid-State Lithium Metal Batteries

被引：24

作者：

Luo, Jing ^{[1
]}

Sun, Qian ^{[1
]}

Liang, Jianwen ^{[1
]}

Adair, Keegan ^{[1
]}

Zhao, Feipeng ^{[1
]}

Deng, Sixu ^{[1
]}

Zhao, Yang ^{[1
]}

Li, Ruying ^{[1
]}

Huang, Huan ^{[2
]}

Yang, Rong ^{[3
]}

Zhao, Shangqian ^{[3
]}

Wang, Jiantao ^{[3
]}

Sun, Xueliang ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Mech & Mat Engn, London, ON N6A 5B9, Canada

[2] Glabat Solid State Battery Inc, London, ON N6G 4X8, Canada

[3] China Automot Battery Res Inst Co Ltd, Beijing 100088, Peoples R China

来源：

ACS ENERGY LETTERS | 2023年 / 8卷 / 09期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

MOLECULAR LAYER DEPOSITION; POLYMER ELECTROLYTES; SUPERIONIC CONDUCTORS; RAMAN-SPECTRA; CRYSTALLINE; INDIUM; COMPATIBILITY; SPECTROSCOPY; SCATTERING; CHEMISTRY;

D O I：

10.1021/acsenergylett.3c01157

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Halide-based solid-state halide electrolytes (SSEs) wererecentlyrevived as promising candidates for next-generation all-solid-statebatteries due to their superionic conductivity, direct compatibilitywith high-voltage cathodes, and scalable production. However, theincompatibility between halide SSEs and lithium metal anodes remainsa main challenge to achieve high energy density. Herein, we demonstratea thin cross-linked poly(butylene oxide) solid polymer electrolyte(xPBO SPE) interlayer on the superionic Li3InCl6 SSE to enable lithium metal compatibility. A rapid and solvent-freein situ cross-linking process is developed by reaction between a 0.5s pulse of trimethylaluminum vapor and the hydroxyl terminal groupsof poly(butylene oxide). The Li-Li symmetric cells using xPBO-SPE@Li3InCl6 demonstrate a highly stable cycling performanceover 1100 h and up to 1.0 mA cm(-2) and 1.0 mAh cm(-2). All-solid-state lithium metal battery (ASSLMB) performancewith a LiCoO2 cathode is presented. This new rapid cross-linkingstrategy shall inspire more possibilities for lithium metal anodeintegration in ASSLMBs.

引用

页码：3676 / 3684

页数：9

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