Evaluation on corrosion mitigation capabilities of nitrogen doped carbon dots as corrosion inhibitors for mild steel in descaling solution

被引:28
作者
Saraswat, Vandana [1 ]
Sarkar, Tarun Kanti [2 ]
Yadav, Mahendra [3 ]
机构
[1] Galgotias Univ, Sch Basic & Appl Sci, Div Chem, Greater Noida, Uttar Pradesh, India
[2] IFTM Univ, Sch Sci, Dept Chem, Moradabad, India
[3] Indian Inst Technol ISM, Dept Chem Engn, Dhanbad, India
关键词
Mild steel; Langmuir isotherm; Mixed type corrosion inhibitors; N80; STEEL; PYRIMIDINE-DERIVATIVES; AMINO-ACID; ADSORPTION; BEHAVIOR; EXTRACT; IRON;
D O I
10.1016/j.matchemphys.2023.128678
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The article represents a mechanistic and detailed evaluation of synthesized novel nitrogen doped carbon dots (NCDs) as corrosion inhibitors for mild steel in 15 % HCl solution. The investigation reflects the synergistic adsorption and corrosion inhibition capabilities of N-CDs. The investigation reflects that the N-CDs display efficient corrosion inhibition of 93.09 % efficiency for a dosage of 350 ppm. The N-CDs adsorb upon the metallic substrate surface to generate a protective layer at the metal solution interface and thereby protect it from the aggressive electrolyte. The electrochemical analyses confirm that the N-CDs behave as mixed type corrosion inhibitors and protect both anodic and cathodic sites of corrosion. The protective film was chemically analyzed through XPS analysis which confirms the inorganic/organic, hybrid nature of the protective film.
引用
收藏
页数:14
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  • [71] Gravimetric, Electrochemical, Surface Morphology, DFT, and Monte Carlo Simulation Studies on Three N-Substituted 2-Aminopyridine Derivatives as Corrosion Inhibitors of Mild Steel in Acidic Medium
    Verma, Chandrabhan
    Olasunkanmi, Lukman O.
    Quadri, Taiwo W.
    Sherif, El-Sayed M.
    Ebenso, Eno E.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (22) : 11870 - 11882
  • [72] Novel carbon dots as effective corrosion inhibitor for N80 steel in 1 M HCl and CO2-saturated 3.5 wt% NaCl solutions
    Wu, Xiaodan
    Li, Jianbo
    Deng, Chaoyi
    Yang, Lan
    Lv, Jie
    Fu, Luoping
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2022, 1250
  • [73] Experimental and theoretical evaluation of two pyridinecarboxaldehyde thiosemicarbazone compounds as corrosion inhibitors for mild steel in hydrochloric acid solution
    Xu, Bin
    Yang, Wenzhong
    Liu, Ying
    Yin, Xiaoshuang
    Gong, Weinan
    Chen, Yizhong
    [J]. CORROSION SCIENCE, 2014, 78 : 260 - 268
  • [74] Nitrogen-doped carbon quantum dots for effective corrosion inhibition of Q235 steel in concentrated sulphuric acid solution
    Xu, Xumin
    Wei, Hongyu
    Liu, Mingguang
    Zhou, Laishui
    Shen, Guozhu
    Li, Qin
    Hussain, Ghulam
    Yang, Fan
    Fathi, Reham
    Chen, Haiji
    Ostrikov, Kostya
    [J]. MATERIALS TODAY COMMUNICATIONS, 2021, 29
  • [75] Studies on Adsorption and Corrosion Inhibitive Properties of Indoline Compounds on N80 Steel in Hydrochloric Acid
    Yadav, M.
    Sarkar, T. K.
    Purkait, Taniya
    [J]. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 2015, 24 (12) : 4975 - 4984
  • [76] Amino acid compounds as eco-friendly corrosion inhibitor for N80 steel in HCl solution: Electrochemical and theoretical approaches
    Yadav, Mahendra
    Sarkar, Tarun Kanti
    Purkait, Taniya
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2015, 212 : 731 - 738
  • [77] Functionalization of citric acid-based carbon dots by imidazole toward novel green corrosion inhibitor for carbon steel
    Yang, Dongping
    Ye, Yuwei
    Su, Yue
    Liu, Shuang
    Gong, Dirong
    Zhao, Haichao
    [J]. JOURNAL OF CLEANER PRODUCTION, 2019, 229 : 180 - 192
  • [78] Amphiphilic carbon dots as high-efficiency corrosion inhibitor for N80 steel in HCl solution: Performance and mechanism investigation
    Yang, Yin
    Lu, Renling
    Chen, Wu
    Mei, Ping
    Lai, Lu
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2022, 649
  • [79] Structure of a novel Benzyl Quinolinium Chloride derivative and its effective corrosion inhibition in 15 wt.% hydrochloric acid
    Yang, Zhen
    Zhan, Fengtao
    Pan, Yuan
    LYu, Zhifeng
    Han, Chengyou
    Hu, YiPeng
    Ding, Pengpeng
    Gao, Tonghai
    Zhou, Xinyuan
    Jiang, Yingnan
    [J]. CORROSION SCIENCE, 2015, 99 : 281 - 294
  • [80] An effective corrosion inhibitor of N doped carbon dots for Q235 steel in 1 M HCl solution
    Ye, Yuwei
    Zou, Yangjun
    Jiang, Zilong
    Yang, Qiumin
    Chen, Liyong
    Guo, Shengda
    Chen, Hao
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 815