Evaluation on corrosion mitigation capabilities of nitrogen doped carbon dots as corrosion inhibitors for mild steel in descaling solution

被引:34
作者
Saraswat, Vandana [1 ]
Sarkar, Tarun Kanti [2 ]
Yadav, Mahendra [3 ]
机构
[1] Galgotias Univ, Sch Basic & Appl Sci, Div Chem, Greater Noida, Uttar Pradesh, India
[2] IFTM Univ, Sch Sci, Dept Chem, Moradabad, India
[3] Indian Inst Technol ISM, Dept Chem Engn, Dhanbad, India
关键词
Mild steel; Langmuir isotherm; Mixed type corrosion inhibitors; N80; STEEL; PYRIMIDINE-DERIVATIVES; AMINO-ACID; ADSORPTION; BEHAVIOR; EXTRACT; IRON;
D O I
10.1016/j.matchemphys.2023.128678
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The article represents a mechanistic and detailed evaluation of synthesized novel nitrogen doped carbon dots (NCDs) as corrosion inhibitors for mild steel in 15 % HCl solution. The investigation reflects the synergistic adsorption and corrosion inhibition capabilities of N-CDs. The investigation reflects that the N-CDs display efficient corrosion inhibition of 93.09 % efficiency for a dosage of 350 ppm. The N-CDs adsorb upon the metallic substrate surface to generate a protective layer at the metal solution interface and thereby protect it from the aggressive electrolyte. The electrochemical analyses confirm that the N-CDs behave as mixed type corrosion inhibitors and protect both anodic and cathodic sites of corrosion. The protective film was chemically analyzed through XPS analysis which confirms the inorganic/organic, hybrid nature of the protective film.
引用
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页数:14
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