Evaluation on corrosion mitigation capabilities of nitrogen doped carbon dots as corrosion inhibitors for mild steel in descaling solution

被引:28
作者
Saraswat, Vandana [1 ]
Sarkar, Tarun Kanti [2 ]
Yadav, Mahendra [3 ]
机构
[1] Galgotias Univ, Sch Basic & Appl Sci, Div Chem, Greater Noida, Uttar Pradesh, India
[2] IFTM Univ, Sch Sci, Dept Chem, Moradabad, India
[3] Indian Inst Technol ISM, Dept Chem Engn, Dhanbad, India
关键词
Mild steel; Langmuir isotherm; Mixed type corrosion inhibitors; N80; STEEL; PYRIMIDINE-DERIVATIVES; AMINO-ACID; ADSORPTION; BEHAVIOR; EXTRACT; IRON;
D O I
10.1016/j.matchemphys.2023.128678
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The article represents a mechanistic and detailed evaluation of synthesized novel nitrogen doped carbon dots (NCDs) as corrosion inhibitors for mild steel in 15 % HCl solution. The investigation reflects the synergistic adsorption and corrosion inhibition capabilities of N-CDs. The investigation reflects that the N-CDs display efficient corrosion inhibition of 93.09 % efficiency for a dosage of 350 ppm. The N-CDs adsorb upon the metallic substrate surface to generate a protective layer at the metal solution interface and thereby protect it from the aggressive electrolyte. The electrochemical analyses confirm that the N-CDs behave as mixed type corrosion inhibitors and protect both anodic and cathodic sites of corrosion. The protective film was chemically analyzed through XPS analysis which confirms the inorganic/organic, hybrid nature of the protective film.
引用
收藏
页数:14
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共 89 条
  • [1] Rhodanine azosulpha drugs as corrosion inhibitors for corrosion of 304 stainless steel in hydrochloric acid solution
    Abdallah, M
    [J]. CORROSION SCIENCE, 2002, 44 (04) : 717 - 728
  • [2] Persian Liquorice extract as a highly efficient sustainable corrosion inhibitor for mild steel in sodium chloride solution
    Alibakhshi, E.
    Ramezanzadeh, M.
    Haddadi, S. A.
    Bahlakeh, G.
    Ramezanzadeh, B.
    Mandavian, M.
    [J]. JOURNAL OF CLEANER PRODUCTION, 2019, 210 : 660 - 672
  • [3] DFT computations and molecular dynamics investigations on conformers of some pyrazinamide derivatives as corrosion inhibitors for aluminum
    Ammouchi, Nesrine
    Allal, Hamza
    Belhocine, Youghourta
    Bettaz, Sarah
    Zouaoui, Emna
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2020, 300
  • [4] Corrosion inhibition and adsorption behaviour of some bis-pyrimidine derivatives on mild steel in acidic medium
    Anusuya, Nagarajan
    Saranya, Jagadeesan
    Sounthari, Palanisamy
    Zarrouk, Abdelkader
    Chitra, Subramanian
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2017, 225 : 406 - 417
  • [5] Imidazolium-derived polymeric ionic liquid as a green inhibitor for corrosion inhibition of mild steel in 1.0 M HCl: Experimental and computational study
    Ardakani, Ebrahim Kamali
    Kowsari, Elaheh
    Ehsani, Ali
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2020, 586
  • [6] Corrosion inhibition properties of iodide ionic liquids for API 5L X52 steel in acid medium
    Arellanes-Lozada, Paulina
    Diaz-Jimenez, Victor
    Hernandez-Cocoletzi, H.
    Nava, Noel
    Olivares-Xometl, Octavio
    Likhanova, Natalya, V
    [J]. CORROSION SCIENCE, 2020, 175
  • [7] Inhibition of corrosion of aluminum in alkaline solution by a novel azo-schiff base: Experiment and theory
    Arjomandi, Jalal
    Moghanni-Bavil-Olyaei, Hamed
    Parvin, Mohammad Hadi
    Lee, Jin Yong
    Ko, Kyoung Chul
    Joshaghani, Mohammad
    Hamidian, Kourosh
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 746 : 185 - 193
  • [8] Ionic liquids derived from α-amino acid ester salts as potent green corrosion inhibitors for mild steel in 1M HCl
    Aslam, Ruby
    Mobin, Mohammad
    Huda
    Obot, Ime B.
    Alamri, Aeshah H.
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2020, 318 (318)
  • [9] Computational and experimental studies on the efficiency of Rosmarinus officinalis polyphenols as green corrosion inhibitors for XC48 steel in acidic medium
    Belakhdar, Amina
    Ferkous, Hana
    Djellali, Souad
    Sahraoui, Rachid
    Lahbib, Hana
    Ben Amor, Yasser
    Erto, Alessandro
    Balsamo, Marco
    Benguerba, Yacine
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2020, 606
  • [10] Nitrogen-doped carbon dots as high-effective inhibitors for carbon steel in acidic medium
    Cao, Shuyun
    Liu, Dan
    Wang, Tianxiang
    Ma, Aijing
    Liu, Chengwei
    Zhuang, Xupin
    Ding, Hui
    Mamba, Bhekie B.
    Gui, Jianzhou
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2021, 616