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Eco-Friendly Biosorption of Uranium from Aqueous Solutions Using Sepiolite-Cavex CA37 Composite Biosorbent
被引:0
|作者:
Erden, Kadriye Esen
[1
]
Donat, Ramazan
[2
]
机构:
[1] Kocaeli Univ, Uzunciftl Nuh Cimento Vocat Sch, TR-41180 Kocaeli, Turkiye
[2] Pamukkale Univ, Fac Sci, Dept Chem, TR-20070 Denizli, Turkiye
关键词:
adsorption;
biosorption;
SCX-37;
sepiolite;
sorption isotherms;
NICKEL SORPTION;
ADSORPTION;
REMOVAL;
METALS;
WATER;
IONS;
ZN2+;
PB2+;
MECHANISMS;
SURFACES;
D O I:
10.1002/clen.202200313
中图分类号:
X [环境科学、安全科学];
学科分类号:
08 ;
0830 ;
摘要:
Cavex CA37 is a dental material used for positive tooth impressions. After the mold is taken, it hardens through a fast-chemical reaction with air, then becomes waste after usage. In this study, natural sepiolite and Cavex CA37 are mixed at certain ratios to obtain a composite SCX-37 biosorbent that is used for the biosorption of UO2+ (2) ions from a synthetic aqueous solution. Parameters affecting biosorption, such as solution pH, ambient temperature, contact time, and UO2+ (2) ion concentration, are investigated. The biosorption of UO2+ (2) ions on SCX-37 reaches equilibrium in 120 min with 97.56% efficiency at 30 degrees C and pH 4. The isotherms (Langmuir, Freundlich, and D-R) and thermodynamic values of the biosorption of UO2+ (2) ions on the SCX-37 biosorbent are calculated according to the obtained data. It is determined that there is a high correlation between experimental results and all three isotherm models. The adsorption capacity is found to be 41.39 mg g(-1). The biosorption of UO2+ (2) ions onto the SCX37 biosorbent is a chemisorption process with an adsorption energy of 40.50 kJ mol(-1).
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