N1-, N2-, and N3-Methyl-4-nitro-1,2,3-triazoles and Metal Complexes Based on Them

被引：0

作者：

Filippova, Yu. V. ^{[1
]}

Krupnova, I. A. ^{[1
]}

Bosov, K. K. ^{[1
]}

Sukhanov, G. T. ^{[1
]}

Sukhanova, A. G. ^{[1
]}

Pivovarova, E. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem & Energet Technol, Siberian Branch, Biisk 659322, Altai Krai, Russia

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2023年 / 96卷 / 03期

关键词：

nitrotriazole; alkylation; regioselectivity; N-methylnitrotriazoles; coordination compounds; ALKYLATION; TRIAZOLES;

D O I：

10.1134/S1070427223030114

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Alkylation of an NH-heterocycle, 4-nitro-1,2,3-triazole, with dimethyl sulfate is accompanied by tandem alkylation-quaternization and yields a complex mixture of products of N-monoalkylation at all the three heteroatoms, N-1, N-2, and N-3, with the significant prevalence of the N3 derivative and product of its further transformation, 1,3-dimethyl-4-nitro-1,2,3-triazolium salt. Previously unknown complexes of N3-methylnitrotriazole with copper(II) and nickel(II) ions were prepared.

引用

页码：366 / 371

页数：6

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