Bimetallic Re(i)/Pt(ii)/Pd(ii) complexes: study of synthesis and properties

被引：0
作者：
Wang, Nan [1 ]
Zhou, Qing-Dong [1 ]
Jia, Zhiyu [1 ]
机构：
[1] Beijing Inst Technol, Sch Chem & Chem Engn, Key Lab Cluster Sci, Beijing Key Lab Photoelect Electrophoton Convers M, Beijing 102488, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2023年 / 47卷 / 23期
基金：
中国国家自然科学基金;
关键词：
ELECTROCATALYTIC REDUCTION; CARBON-DIOXIDE; HETEROBIMETALLIC COMPLEXES; ENERGY-TRANSFER; ELECTRON; LIGAND; CO2; RU; PHOTOPHYSICS; SUBSTITUENT;
D O I：
10.1039/d3nj00965c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of novel Re(i)-based heterobimetallic complexes were synthesized using the ligand p-[N-2-(2'-pyridyl)benzimidazolyl]-[N-2-(2'-pyridyl)indolyl]-benzene (L1), which contains two distinct N<^>N- and N<^>C-chelating sites. Their photophysical and electrochemical properties were fully characterized, which unveil the existence of electronic communication between the two metal centers. An electrochemical study shows that these types of Re(i) complex are promising candidates as catalysts for electrocatalytic CO2 reduction.
引用
收藏
页码：11210 / 11215
页数：6
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