A Highly Selective Fluorescence Sensor based on Quinoline for the Fluorescence Detection of Al3+ in Aqueous

被引:1
作者
Wang, Jixia [1 ]
Hou, Juanjuan [1 ]
Jiang, Pengwei [2 ,3 ]
Zhang, Yaling [1 ]
Li, Jiankun [1 ]
Wu, Shang [2 ,3 ]
Zhan, Huiying [1 ]
Yang, Quanlu [1 ]
机构
[1] Lanzhou Univ Arts & Sci, Coll Chem Engn, Beimiantan 400, Lanzhou 730000, Gansu, Peoples R China
[2] Northwest Minzu Univ, Gansu Prov Biomass Funct Composites Engn Res Ctr, Key Lab Environm Friendly Composite Mat, Key Lab Util Environm Friendly Composite Mat & Bio, Lanzhou 730030, Peoples R China
[3] Northwest Minzu Univ, Coll Chem Engn, Lanzhou 730030, Peoples R China
基金
中国国家自然科学基金;
关键词
Chemosensor; fluorescent; metal ion recognition; quinolone; chemical sensor; ultra-trace; TERT-BUTYLHYDROQUINONE; RECOGNITION; PROBE; IONS;
D O I
10.2174/1570178619666220818151718
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Specific recognition of ultra-trace levels of ions in semi-water using super-quicker methods is still a challenge for environmental monitoring. The development of ion-selective fluorescence sensors for selective detection of Al3+ is an essential task because of the importance of Al3+ to the human body. A fluorescent chemosensor S based on quinoline as a binding and signaling unit has been designed and synthesized in a one-step procedure. More importantly, when Al3+ ions are added to the sensor S, it showed immediate responses toward Al3+ ions in dimethylformamide (DMF) solution with the strong blue fluorescence quenching. And the S detection limit (LOD) of Al3+ in aqueous media (1.0 M) is 1.75x10(-7) M. Furthermore, the proposed mechanism of action for sensor S and metal ions has been learned using some research techniques such as FE-SEM, FT-IR, XRD and XPS. Further, the fluorescence chemical sensor specifically recognizes the metal aluminum ion.
引用
收藏
页码:91 / 96
页数:6
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