Smart design strategies of metal-based compounds for electrochemical CO2 reduction: From microscopic structure to atomic-level active site

被引：2

作者：

Zhang, Tong ^{[1
]}

Tang, Yu-Feng ^{[1
]}

Yu, Mulin ^{[1
]}

Liu, Shuo ^{[1
]}

Liu, Lin-Bo ^{[1
]}

Fu, Xian-Zhu ^{[2
]}

Luo, Jing-Li ^{[2
,3
]}

Liu, Subiao ^{[1
]}

机构：

[1] Cent South Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Hunan, Peoples R China

[2] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen, Peoples R China

[3] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 1H9, Canada

来源：

CHEM CATALYSIS | 2024年 / 4卷 / 02期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE ELECTROREDUCTION; CORE-SHELL STRUCTURE; SELECTIVE ELECTROREDUCTION; TUNING NANOCAVITIES; EFFICIENT; CATALYSTS; CU2O; NANOPARTICLES; SURFACE; ARRAYS;

D O I：

10.1016/j.checat.2024.100906

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemical CO2 reduction (CO2RR) to valuable products enables an artificial carbon -neutral electrosynthesis via integrating renewable energy resources. Various electrocatalysts have been studied with varying degrees of success from various viewpoints toward CO2RR. Among them, metal -based compounds hold great potential to drive industrial -scale CO2RR upon taking the scarcity, the reserve, the cost, the preparation complexity, and the practical application into consideration as a whole. However, a comprehensive coverage on smart design strategies of specific nanostructures of metal -based compounds is still lacking. This review thus challenges the position to discuss various design strategies and their resultant properties benefiting from various specific nanostructures of metal -based compounds in depth. Furthermore, the effects induced by the specific nanostructures are dissected to unlock the nanostructure-property-activity relationships and the underlying mechanisms. In addition, the issues and challenges that this technology faces on metal -based compounds with various specific nanostructures toward CO2RR are suggested.

引用

页数：22

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