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Thermophysical Study on the Mixing Properties of Mixtures Comprising 2-(2-Methoxyethoxy)ethanol, Butan-1-ol, Butan-2-ol, and Propan-1-ol
被引:2
|作者:
Lifi, Mohamed
[1
]
Abala, Ilham
[2
]
Briones-Llorente, Raul
[3
]
Munoz-Rujas, Natalia
[4
]
Aguilar, Fernando
[4
]
Alaoui, Fatima Ezzahrae M'hamdi
[5
]
机构:
[1] Univ Valladolid, Grp Energia Econ & Dinam Sistemas GEEDS, Valladolid 47011, Spain
[2] Chouaib Doukkali Univ, Dept Chem, Fac Sci, El Jadida 24000, Morocco
[3] Univ Burgos, Fac Sci, Dept Math & Comp, Energy Engn Res Grp iENERGIA, Burgos 09001, Spain
[4] Univ Burgos, Escuela Politecn Super, Dept Ingn Electromecan, Burgos 09006, Spain
[5] Abdelmalek Essaadi Univ, Fac Sci, Energet Lab, Tetouan 93002, Morocco
关键词:
EXCESS MOLAR VOLUMES;
ORGANIC-SOLVENT MIXTURES;
DIETHYL CARBONATE PLUS;
BINARY-LIQUID MIXTURES;
PERTURBED-CHAIN SAFT;
TERT-BUTYL ETHER;
N-ALKOXYETHANOLS;
REFRACTIVE-INDEXES;
THERMODYNAMIC PROPERTIES;
OXYGENATED ADDITIVES;
D O I:
10.1021/acs.jced.3c00320
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
Excess enthalpy (H-E), dynamic and kinematic viscosities (eta, upsilon), density (rho), and refractive index (n(D)) of mixtures comprising 2-(2-methoxyethoxy)ethanol, butan-1-ol, butan-2-ol, and propan-1-ol are presented at p = 0.1 MPa and at T = 298.15 and 313.15 K. Deviations in refractive index (Delta n(D)) is generated from experimental data of refractive index. Experimental data of rho for all binary mixtures are predicted using the PC-SAFT (Perturbed Chain-Statistical Associating Fluid) EoS. Furthermore, H-E and Delta n(D) are adjusted using the Redlich-Kister equation. However, the correlation of measured data of H-E is performed by using the UNIQUAC and NRTL models.
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页码:3062 / 3076
页数:15
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