Simulation study on the coupled heat and mass transfer of CO2 in a heavy oil-water liquid system based on an improved lattice Boltzmann (LB) method

This study investigates the heat and mass transfer when low-temperature CO2 diffuses in a heavy oil-water liquid system based on an improved Lattice Boltzmann (LB) method. First, we determine the CO2 diffusion coefficients in heavy oil and water and the heat transfer coefficients of heavy oil and water using the pressure drop (DP) method and the laser flash (LF) method, respectively. Then, a numerical model that couples the heat and mass transfer in the system is established based on the improved LB method. The effect of low-temperature CO2 on the temperature field of the system and the effect of changes in the temperature field on CO2 diffusion are investigated. Finally, we develop a micro-model reproducing the heat and mass transfer of CO2 in water and heavy oilsaturated porous media to validate the accuracy of the numerical model. The results demonstrate that the CO2 diffusion coefficients in heavy oil and water linearly increase with the temperature increases. The heat transfer coefficients of heavy oil and water are insensitive to the changes in temperature. The heat transfer process has a great impact on the mass transfer of CO2 in the liquid system. The CO2 diffusion velocity slows down as the system temperature decreases because of the heat transfer (from 400 K to 300 K), leading to a reduction percentage of 300 % in the CO2 front movement velocity. Compared to the scenarios neglecting heat transfer, CO2 diffusion distance and amount decrease by 38 % and 50 %, respectively because of the changes in the temperature field of the system.