On the Road to the Frontiers of Lithium-Ion Batteries: A Review and Outlook of Graphene Anodes

被引:157
作者
Bi, Jingxuan [1 ,2 ]
Du, Zhuzhu [1 ,2 ]
Sun, Jinmeng [1 ,2 ]
Liu, Yuhang [1 ,2 ]
Wang, Ke [1 ,2 ]
Du, Hongfang [3 ]
Ai, Wei [1 ,2 ]
Huang, Wei [1 ,2 ,3 ,4 ,5 ]
机构
[1] Northwestern Polytech Univ, Frontiers Sci Ctr Flexible Elect FSCFE, 127 West Youyi Rd, Xian 710072, Peoples R China
[2] Northwestern Polytech Univ, Xian Inst Flexible Elect IFE, 127 West Youyi Rd, Xian 710072, Peoples R China
[3] Fujian Normal Univ, Strait Inst Flexible Elect SIFE, Strait Lab Flexible Elect SLoFE, Future Technol, Fuzhou 350117, Peoples R China
[4] Nanjing Tech Univ NanjingTech, Sch Flexible Elect Future Technol, Key Lab Flexible Elect KLOFE, 30 South Puzhu Rd, Nanjing 211816, Peoples R China
[5] Nanjing Tech Univ NanjingTech, Sch Flexible Elect Future Technol, Inst Adv Mat IAM, 30 South Puzhu Rd, Nanjing 211816, Peoples R China
基金
美国国家科学基金会; 中国国家自然科学基金;
关键词
anodes; doped graphene; functionalized graphene; graphene; lithium-ion batteries; NITROGEN-DOPED GRAPHENE; HIGH-PERFORMANCE ANODE; FEW-LAYER GRAPHENE; ENHANCED ELECTROCHEMICAL PERFORMANCE; IN-SITU FABRICATION; BINDER-FREE ANODE; TUNABLE SURFACE FUNCTIONALITIES; MULTIWALLED CARBON NANOTUBES; GRAPHITIC OXIDE CELLS; LI STORAGE PROPERTIES;
D O I
10.1002/adma.202210734
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene has long been recognized as a potential anode for next-generation lithium-ion batteries (LIBs). The past decade has witnessed the rapid advancement of graphene anodes, and considerable breakthroughs are achieved so far. In this review, the aim is to provide a research roadmap of graphene anodes toward practical LIBs. The Li storage mechanism of graphene is started with and then the approaches to improve its electrochemical performance are comprehensively summarized. First, morphologically engineered graphene anodes with porous, spheric, ribboned, defective and holey structures display improved capacity and rate performance owing to their highly accessible surface area, interconnected diffusion channels, and sufficient active sites. Surface-modified graphene anodes with less aggregation, fast electrons/ions transportation, and optimal solid electrolyte interphase are discussed, demonstrating the close connection between the surface structure and electrochemical activity of graphene. Second, graphene derivatives anodes prepared by heteroatom doping and covalent functionalization are outlined, which show great advantages in boosting the Li storage performances because of the additionally introduced defect/active sites for further Li accommodation. Furthermore, binder-free and free-standing graphene electrodes are presented, exhibiting great prospects for high-energy-density and flexible LIBs. Finally, the remaining challenges and future opportunities of practically available graphene anodes for advanced LIBs are highlighted.
引用
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页数:42
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