[Me3N(C6H3(CF3)2)][BF4] and [Me3N(C6H3(CH3)2)][BF4], as potential synthons for non-covalent supramolecular assembly

被引：1

作者：

Schmid, Jonas R. ^{[2
]}

Wiesner, Anja ^{[2
]}

Vossnacker, Patrick ^{[2
]}

Jansen, Martin ^{[1
]}

Riedel, Sebastian ^{[2
]}

机构：

[1] Max Planck Inst Festkorperforschung, Heisenbergstr 1, D-70569 Stuttgart, Germany

[2] Free Univ Berlin, Inst Chem & Biochem, Anorgan Chem, Fabeckstr 34-36, D-14195 Berlin, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2024年 / 79卷 / 01期

关键词：

crystal structure; crystal engineering; cations; fluorine; LONG-RANGE;

D O I：

10.1515/znb-2023-0095

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds [Me3N(C6H3(CF3)(2))][BF4] and [Me3N(C6H3(CH3)(2))][BF4] were synthesized from commercially available starting materials and fully characterized by single-crystal X-ray diffraction, NMR, IR and Raman spectroscopy, as well as mass spectrometry. Both ammonium cations show potential for applications in crystal engineering due to their structure directing properties in the solid state.

引用

页码：57 / 61

页数：5

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