Eletrocarboxylation Reactions Using CO2 Both as Promoter and Carboxylative Reagent

被引:22
作者
Zhang, Ke [1 ]
Liu, Xiao-Fei [1 ]
Ren, Wei-Min [1 ]
Lu, Xiao-Bing [1 ]
Zhang, Wen-Zhen [1 ]
机构
[1] Dalian Univ Technol, Frontiers Sci Ctr Smart Mat, State Key Lab Fine Chem, Dalian 116024, Peoples R China
基金
中国国家自然科学基金;
关键词
carbon dioxide fixation; carboxylation; carboxylic acids; organic electrosynthesis; promoter; CARBON-DIOXIDE; ELECTROCHEMICAL CARBOXYLATION; SUBSTITUTED ALKENES; ACIDS; DICARBOXYLATION; REDUCTION; ALCOHOLS;
D O I
10.1002/chem.202204073
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrocarboxylation reaction, which employs organic electrosynthesis to achieve the utilization of CO2 as a carboxylative reagent, provides a powerful and efficient tool for the preparation of organic carboxylic acid. In some electrocarboxylation reactions, CO2 also acts as a promoter to facilitate the desired reaction. This concept mainly highlights recent CO2-promoted electrocarboxylation reactions via CO2 center dot- intermediate or transiently protective carboxylation of active intermediate with CO2.
引用
收藏
页数:6
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