Eletrocarboxylation Reactions Using CO2 Both as Promoter and Carboxylative Reagent

被引：22

作者：

Zhang, Ke ^{[1
]}

Liu, Xiao-Fei ^{[1
]}

Ren, Wei-Min ^{[1
]}

Lu, Xiao-Bing ^{[1
]}

Zhang, Wen-Zhen ^{[1
]}

机构：

[1] Dalian Univ Technol, Frontiers Sci Ctr Smart Mat, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2023年 / 29卷 / 32期

基金：

中国国家自然科学基金;

关键词：

carbon dioxide fixation; carboxylation; carboxylic acids; organic electrosynthesis; promoter; CARBON-DIOXIDE; ELECTROCHEMICAL CARBOXYLATION; SUBSTITUTED ALKENES; ACIDS; DICARBOXYLATION; REDUCTION; ALCOHOLS;

D O I：

10.1002/chem.202204073

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrocarboxylation reaction, which employs organic electrosynthesis to achieve the utilization of CO2 as a carboxylative reagent, provides a powerful and efficient tool for the preparation of organic carboxylic acid. In some electrocarboxylation reactions, CO2 also acts as a promoter to facilitate the desired reaction. This concept mainly highlights recent CO2-promoted electrocarboxylation reactions via CO2 center dot- intermediate or transiently protective carboxylation of active intermediate with CO2.

引用

页数：6

共 52 条

[1] Harnessing Applied Potential: Selective β-Hydrocarboxylation of Substituted Olefins [J].

Alkayal, Anas ;

Tabas, Volodymyr ;

Montanaro, Stephanie ;

Wright, Iain A. ;

Malkov, Andrei V. ;

Buckley, Benjamin R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (04) :1780-1785

[2]

Beil S. B., 2021, ANGEW CHEM, V133, P14874

[3] Reproducibility in Electroorganic Synthesis-Myths and Misunderstandings [J].

Beil, Sebastian B. ;

Pollok, Dennis ;

Waldvogel, Siegfried R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (27) :14750-14759

[4] Molecular catalysis of CO2reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes [J].

Boutin, E. ;

Merakeb, L. ;

Ma, B. ;

Boudy, B. ;

Wang, M. ;

Bonin, J. ;

Anxolabehere-Mallart, E. ;

Robert, M. .

CHEMICAL SOCIETY REVIEWS, 2020, 49 (16) :5772-5809

[5] Photochemical and Electrochemical Carbon Dioxide Utilization with Organic Compounds [J].

Cao, Yu ;

He, Xing ;

Wang, Ning ;

Li, Hong-Ru ;

He, Liang-Nian .

CHINESE JOURNAL OF CHEMISTRY, 2018, 36 (07) :644-659

[6] Recent Applications of Homogeneous Catalysis in Electrochemical Organic Synthesis [J].

Cheng, Xu ;

Lei, Aiwen ;

Mei, Tian-Sheng ;

Xu, Hai-Chao ;

Xu, Kun ;

Zeng, Chengchu .

CCS CHEMISTRY, 2022, 4 (04) :1120-1152

[7] Concepts and tools for mechanism and selectivity analysis in synthetic organic electrochemistry [J].

Costentin, Cyrille ;

Saveant, Jean-Michel .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2019, 116 (23) :11147-11152

[8] Carbon dioxide-promoted palladium-catalyzed dehydration of primary allylic alcohols: access to substituted 1,3-dienes [J].

Huang, Yan-Kai ;

Zhang, Wen-Zhen ;

Zhang, Ke ;

Wang, Wen-Le ;

Lu, Xiao-Bing .

ORGANIC CHEMISTRY FRONTIERS, 2021, 8 (05) :941-946

[9] The applications of electrochemical synthesis in asymmetric catalysis [J].

Jiao, Ke-Jin ;

Wang, Zhen-Hua ;

Ma, Cong ;

Liu, Hui-Lin ;

Cheng, Bin ;

Mei, Tian-Sheng .

CHEM CATALYSIS, 2022, 2 (11) :3019-3047

[10] Carbon Dioxide-Mediated C(sp2)-H Arylation of Primary and Secondary Benzylamines [J].

Kapoor, Mohit ;

Chand-Thakuri, Pratibha ;

Young, Michael C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (19) :7980-7989

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