In Situ Formation of Frustrated Lewis Pairs in a Zirconium Metal-Organic Cage for Sustainable CO2 Chemical Fixation

被引：16

作者：

Chen, Cheng-Xia ^{[1
,2
]}

Rabaa, Hassan ^{[1
,3
]}

Wang, Haiping ^{[1
]}

Lan, Pui Ching ^{[1
]}

Xiong, Yang-Yang

Wei, Zhang-Wen ^{[2
]}

Al-Enizi, Abdullah M. ^{[4
]}

Nafady, Ayman ^{[4
]}

Ma, Shengqian ^{[1
]}

机构：

[1] Univ North Texas, Dept Chem, Denton, TX 76201 USA

[2] Sun Yat Sen Univ, Lehn Inst Funct Mat, Sch Chem, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China

[3] Ibn Tofail Univ, Dept Chem, ESCTM, Kenitra 14000, Morocco

[4] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia

来源：

CCS CHEMISTRY | 2023年 / 5卷 / 09期

关键词：

metal-organic cage; frustrated Lewis pair; heterogeneous catalysis; CO2; conversion; sustain- able chemistry; CARBON-DIOXIDE; C-H; CATALYTIC-REDUCTION; METHANOL; HYDROGENATION; ACTIVATION; CHEMISTRY; HYDROSILYLATION; CONSTRUCTION; METHYLATION;

D O I：

10.31635/ccschem.023.202302856

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sustainable CO2 fixation represents a facile and promising approach to constructing various valueadded chemicals. Herein, we contribute a robust metal-organic cage (MOC), denoted as TCPB-1, comprising a bulky Lewis acid functionalized linker, which can in situ form frustrated Lewis pairs (FLPs) upon the addition of Lewis basic substrates to efficiently drive CO2 transformation. Significantly, the incorporation of Lewis acidic boron sites within TCPB-1 promedicinal benzimidazole derivatives via an FLPmediated pathway, and boosts the stability/durability of the FLP catalyst. In addition, the underlying bined experimental and molecular simulation studcule activation and beyond.

引用

页码：1989 / 1998

页数：10

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