Power-free bipolar membrane electrodialysis for acid-alkali production in river estuaries

被引：11

作者：

Zhang, Zirui ^{[1
]}

Luo, Fabao ^{[1
,2
]}

Jiang, Chenxiao ^{[1
]}

Xu, Tongwen ^{[1
]}

机构：

[1] Univ Sci & Technol China, Sch Chem & Mat Sci, Anhui Prov Engn Lab Funct Membrane Mat, Hefei 230026, Anhui, Peoples R China

[2] Hefei Normal Univ, Sch Chem & Chem Engn, Hefei 230061, Peoples R China

来源：

CHEMICAL ENGINEERING SCIENCE | 2023年 / 273卷

关键词：

Salinity gradient energy; Bipolar membrane electrodialysis; Membrane module; Bulk video imaging; Process optimization; WATER-DISSOCIATION; ENERGY-CONVERSION; TRANSPORT; ELECTROLYSIS;

D O I：

10.1016/j.ces.2023.118643

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Recent studies suggest that 2-2.6 TW blue energy can be harvested by mixing coastal seawater with freshwater world widely, but the extractable part was limited due to undesired development of conver-sion techniques. In this study, a novel power-free bipolar membrane electrodialysis process is proposed for the closed-loop utilization of salinity gradient energy and the salt resources in seawater. The system was evaluated using theoretical and experimental methods. Significance of the various membrane mod-ules and operational conditions was evaluated. Based on fluid dynamics simulations and fluid online imaging technologies, a prototype electro-membrane reactor was fabricated to maximize the achievable energy and acid/base products. The acid production rate reached 6.9 mmol h-1 when feeding simulated seawater (30 g/L NaCl) and river water (1 g/L NaCl). The protocols provided in this work offer an effective route for developing advanced membrane processes for the harvesting of salinity gradient energy and acid-alkali production.@2023 Elsevier Ltd. All rights reserved.

引用

页数：9

共 42 条

[1] Biodegradability as an Off-Ramp for the Circular Economy: Investigations into Biodegradable Polymers for Home and Personal Care [J].

Backer, Scott A. ;

Leal, Lyndsay .

ACCOUNTS OF CHEMICAL RESEARCH, 2022, 55 (15) :2011-2018

[2] A Redox-Shuttled Electrochemical Method for Energy-Efficient Separation of Salt from Water [J].

Beh, Eugene S. ;

Benedict, Michael A. ;

Desai, Divyaraj ;

Rivest, Jessy B. .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (15) :13411-13417

[3] The statistical geometry of material loops in turbulence [J].

Bentkamp, Lukas ;

Drivas, Theodore D. ;

Lalescu, Cristian C. ;

Wilczek, Michael .

NATURE COMMUNICATIONS, 2022, 13 (01)

[4] Membrane research beyond materials science [J].

Beuscher, U. ;

Kappert, E. J. ;

Wijmans, J. G. .

JOURNAL OF MEMBRANE SCIENCE, 2022, 643

[5] Self-attenuation of extreme events in Navier-Stokes turbulence [J].

Buaria, Dhawal ;

Pumir, Alain ;

Bodenschatz, Eberhard .

NATURE COMMUNICATIONS, 2020, 11 (01)

[6]

Chen L.H.K., 2022, NAT COMMUN, V13

[7] Water-Dissociation-Assisted Electrolysis for Hydrogen Production in a Salinity Power Cell [J].

Chen, Xia ;

Jiang, Chenxiao ;

Shehzad, Muhammad Aamir ;

Wang, Yaoming ;

Feng, Hongyan ;

Yang, Zhengjin ;

Xu, Tongwen .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (15) :13023-13030

[8] Storable hydrogen production by Reverse Electro-Electrodialysis (REED) [J].

Chen, Xia ;

Jiang, Chenxiao ;

Zhang, Yilue ;

Wang, Yaoming ;

Xu, Tongwen .

JOURNAL OF MEMBRANE SCIENCE, 2017, 544 :397-405

[9] On the modelling of an Acid/Base Flow Battery: An innovative electrical energy storage device based on pH and salinity gradients [J].

Culcasi, Andrea ;

Gurreri, Luigi ;

Zaffora, Andrea ;

Cosenza, Alessandro ;

Tamburini, Alessandro ;

Micale, Giorgio .

APPLIED ENERGY, 2020, 277

[10] Electrolyte transport through amphoteric nanofiltration membranes [J].

Fievet, P ;

Labbez, C ;

Szymczyk, A ;

Vidonne, A ;

Foissy, A ;

Pagetti, J .

CHEMICAL ENGINEERING SCIENCE, 2002, 57 (15) :2921-2931

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