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Single particle inductively coupled plasma mass spectrometry and its variations for the analysis of nanoparticles
被引:1
作者:
Zhou, Zichao
[1
]
Beauchemin, Diane
[1
]
机构:
[1] Queens Univ, Dept Chem, 90 Bader Lane, Kingston, ON K7L 3N6, Canada
基金:
加拿大自然科学与工程研究理事会;
关键词:
SAMPLE INTRODUCTION SYSTEM;
MIXED-GAS PLASMA;
SILVER NANOPARTICLES;
ICP-MS;
COLLOID ANALYSIS;
FLOW-INJECTION;
PLATINUM NANOPARTICLES;
TRANSPORT EFFICIENCY;
NUMBER CONCENTRATION;
SIZE;
D O I:
10.1039/d3cc04974d
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Single particle inductively coupled plasma mass spectrometry (spICPMS) can count and weigh metal-containing nanoparticles (NPs), enabling their sizing if their geometry, density, and composition are known. With a nebulizer and a spray chamber for sample introduction, both the sample uptake rate and the transport efficiency must be determined when calibrating with solutions. In contrast, flow injection (FI) and mono-segmented flow analysis (MSFA) coupled to spICPMS do not need determination of the transport efficiency and sample uptake rate for accurate NP mass measurement. Correcting for the significant settling time on some instruments is also discussed, as well as calibration through signal integration instead of averaging, which eliminates the need to measure the transport efficiency when seeking NP mass. Nitrogen added to the outer plasma gas can reduce the background for the determination of P, S, Ca and Fe. Infrared heating of the sample introduction system provides 100% transport efficiency, enabling accurate particle mass and concentration measurements without measurement of transport efficiency. Single particle inductively coupled plasma mass spectrometry (spICPMS) can count and weigh metal-containing nanoparticles (NPs), enabling their sizing if their geometry, density, and composition are known.
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页码:1826 / 1839
页数:15
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