Effects of heating rate on mechanical and dielectric properties of the Si3N4f/BN/Si3N4 composites by PIP

被引：4

作者：

Meng, Nan ^{[1
]}

Liu, Chidong ^{[1
]}

Ye, Fang ^{[1
]}

Cheng, Laifei ^{[1
]}

Zhou, Jie ^{[1
]}

Li, Mingxing ^{[1
]}

Li, Shenghao ^{[1
]}

Cui, Xuefeng ^{[1
]}

机构：

[1] Northwestern Polytech Univ, Sci & Technol Thermostructural Composite Mat Lab, Xian 710072, Peoples R China

来源：

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T | 2023年 / 22卷

基金：

中国国家自然科学基金;

关键词：

BN; PIP; Heating rate; Interfacial shear strength; Mechanical properties; Dielectric properties; SILICON-NITRIDE CERAMICS; PYROLYSIS TEMPERATURES; BEHAVIOR; POLYVINYLSILAZANE; CARBONIZATION; PERFORMANCE; PRECURSOR; AEROSPACE; DESIGN; SICN;

D O I：

10.1016/j.jmrt.2022.12.175

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The fabrication of silicon nitride (Si3N4) fiber-reinforced boron nitride (BN) and Si3N4 matrix (Si3N4f/BN/Si3N4) composites with BN interphase through precursor infiltration and pyrolysis (PIP) process is reported. The effects of heating rate during PIP process on mechanical and dielectric properties of composites are analyzed. When the heating rate is 5 degrees C/min, the overall performance of Si3N4f/BN/Si3N4 composites is optimal, and the flexural strength and fracture toughness attain 138 MPa and 5.7 MPa m1/2, and the dielectric constant and dielectric loss are 3.90 and 0.008, respectively. The composites achieve a synergy combining structural with functional properties. The influence mechanism of the heating rate during PIP process on the Si3N4f/BN/Si3N4 composites disclose the following. First, the heating rate makes an effect on the carbon content in the Si3N4 matrix, and consequently the dielectric properties of the composites are changed. Second, at 8 degrees C/min, the modulus of Si3N4 matrix is the lowest due to the existence of nanopores. At 2 degrees C/min, the strong axial tensile stress results in severe cracking of the Si3N4 matrix, so the matrix modulus decrease. Third, the heating rate strongly affects the radial stress state at the interphase, which affects the interfacial shear strength of the composites. The matrix modulus and interfacial shear strength can be optimized at 5 degrees C/min to improve the mechanical properties of the composites.(c) 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CCBY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

引用

页码：3463 / 3474

页数：12

共 46 条

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