Green Synthesis of Magnetic Supramolecules β-Cyclodextrin/Iron Oxide Nanoparticles for Photocatalytic and Antibacterial Applications

被引：13
作者：
Almutairi, Tahani M. [1 ]
Al-Rasheed, Hessa H. [1 ]
Alaqil, Zainab M. [1 ]
Hajri, Amira K. [2 ]
Elsayed, Nadia H. [3 ]
机构：
[1] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
[2] Univ Tabuk, Alwajh Coll, Dept Chem, Tabuk 47512, Saudi Arabia
[3] Natl Res Ctr, Dept Polymers & Pigments, Cairo 12311, Egypt
来源：
ACS OMEGA | 2023年 / 8卷 / 35期
关键词：
FE3O4; NANOPARTICLES; EFFICIENT ADSORPTION; SILVER NANOPARTICLES; AQUEOUS-SOLUTIONS; METHYLENE-BLUE; ANTIOXIDANT; REMOVAL; FABRICATION; MECHANISM; EXTRACT;
D O I：
10.1021/acsomega.3c04117
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Iron oxide nanoparticles (Fe(3)O(4)NPs) are a fascinating field of study due to their wide range of practical applications in environmental and medical contexts. This study presents a straightforward, environmentally friendly method for producing Fe(3)O(4)NPs utilizing ss-cyclodextrin (ss-CD) as a reducing and capping agent. This approach results in the rapid and effective eco-friendly synthesis of ss-CD/Fe(3)O(4)NPs. The properties and characteristics of ss-CD/Fe(3)O(4)NPs were investigated using various methods, including ultraviolet-visible (UV/vis) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), thermogravimetry analysis (TGA), and vibrating-sample magnetometry (VSM). The absorption of ss CD/Fe(3)O(4)NPs caused a distinct peak at 349 nm, as evidenced by the results of UV/vis studies. This peak was attributed to the absorption of surface plasmon resonance. The crystalline nature of ss-CD/Fe(3)O(4)NPs was confirmed through XRD analysis. The SEM and TEM analyses have verified the geometry and structural characteristics of ss-CD/Fe(3)O(4)NPs. The ss-CD/Fe(3)O(4)NPs exhibited remarkable effectiveness in the decomposing efficiency (%) of methylene blue (MB) dye with 52.2, 94.1, and 100% for 0.2, 0.4, and 0.6 g ss-CD/ Fe(3)O(4)NPs, respectively. In addition, the highest efficiency in hunting radicals was observed (347.2 +/- 8.2 mg/g) at 100 mg/mL ss CD/Fe(3)O(4)NPs; the combination of ss-CD/Fe(3)O(4)NPs exhibited remarkable effectiveness in inhibiting the growth of some bacteria that cause infections. The capabilities of ss-CD/Fe(3)O(4)NPs for various applications showed that these materials could be used in photocatalytic, antioxidants, and antibacterial. Additionally, the eco-friendly synthesis of these materials makes them a promising option for the remediation of harmful pollutants and microbes.
引用
收藏
页码：32067 / 32077
页数：11
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