The Effects of Shear Parameters on the Stability of Emulsion Explosive Matrices

被引:0
作者
Zhou, Jianmin [1 ,2 ,4 ]
Jia, Yongsheng [1 ]
Yao, Yingkang [2 ]
Xie, Xianqi [1 ]
Zhao, Mingsheng [3 ,4 ]
机构
[1] Jianghan Univ, State Key Lab Precis Blasting, Wuhan 430010, Peoples R China
[2] Jianghan Univ, Hubei Key Lab Blasting Engn, Wuhan 430010, Peoples R China
[3] Univ Guizhou, Guiyang 550001, Guizhou, Peoples R China
[4] Poly Xinlian Blasting Engn Grp Co Ltd, Guiyang 550002, Peoples R China
基金
中国国家自然科学基金;
关键词
emulsion explosive matrices; shear stability; droplet size; shear parameter; IN-OIL EMULSIONS; CONCENTRATED EMULSIONS; RHEOLOGICAL PROPERTIES; BREAKUP; DEFORMATION; DROPLETS; EMULSIFICATION; PARTICLES; STEADY; FLUIDS;
D O I
10.1134/S1061933X23600872
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work demonstrated the criterion of shear stability of emulsion explosive matrices (EEM), combined with rheology test, interfacial tension test, droplet size test and the crystallization test of emulsion explosive matrices. The shear stability of emulsion explosive matrices was defined as the characteristic refinement time of the droplet size decrease in emulsification process. The constitutive relationship between the characteristic refinement time and droplet size of inner phase droplets was proposed by theoretical analysis and experiments on the emulsification process of emulsion explosive matrices. By analyzing the relationship between rheological properties and characteristic refinement time of emulsion explosive matrices, the relationship model between Bingham coefficient and dimensionless coefficient was established to characterize the shear stability of emulsion explosive matrices. The effects of shear strength, shear time and shear shape on the stability of emulsion explosive matrices were studied. In addition, there exists a critical value to quantitatively characterize the shear stability of emulsion explosive matrices.
引用
收藏
页码:153 / 168
页数:16
相关论文
共 30 条
[1]   Deformation and breakup of a viscoelastic drop in a Newtonian matrix under steady shear [J].
Aggarwal, Nishith ;
Sarkar, Kausik .
JOURNAL OF FLUID MECHANICS, 2007, 584 (1-21) :1-21
[2]   AN EXPERIMENTAL INVESTIGATION OF DROP DEFORMATION AND BREAKUP IN STEADY, TWO-DIMENSIONAL LINEAR FLOWS [J].
BENTLEY, BJ ;
LEAL, LG .
JOURNAL OF FLUID MECHANICS, 1986, 167 :241-283
[3]   KINETICALLY INDUCED ORDERING IN GELATION OF EMULSIONS [J].
BIBETTE, J ;
MASON, TG ;
GANG, H ;
WEITZ, DA .
PHYSICAL REVIEW LETTERS, 1992, 69 (06) :981-984
[4]   TIPSTREAMING OF DROPS IN SIMPLE SHEAR FLOWS [J].
DEBRUIJN, RA .
CHEMICAL ENGINEERING SCIENCE, 1993, 48 (02) :277-284
[5]   Shear rupturing of complex fluids: Application to the preparation of quasi-monodisperse water-in-oil-in-water double emulsions [J].
Goubault, C ;
Pays, K ;
Olea, D ;
Gorria, P ;
Bibette, J ;
Schmitt, V ;
Leal-Calderon, F .
LANGMUIR, 2001, 17 (17) :5184-5188
[6]   DEFORMATION AND BREAKUP OF LIQUID DROPLETS IN A SIMPLE SHEAR FIELD [J].
KARAM, HJ ;
BELLINGE.JC .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1968, 7 (04) :576-&
[7]  
Li K., 2007, EXPLOS MAT, V36, P33, DOI DOI 10.3969/J.ISSN.1001-8352.2007.06.011
[8]  
Liu J., 2015, EXPLOS MAT, V44, P38, DOI DOI 10.3969/J.ISSN.1001-8352.2015.06.009
[9]   Monodisperse fragmentation in emulsions: Mechanisms and kinetics [J].
Mabille, C ;
Leal-Calderon, L ;
Bibette, J ;
Schmitt, V .
EUROPHYSICS LETTERS, 2003, 61 (05) :708-714
[10]   Effect of silica particles on stability of highly concentrated water-in-oil emulsions with non-ionic surfactant [J].
Masalova, I. ;
Kharatyan, E. .
COLLOID JOURNAL, 2013, 75 (01) :95-102