Adsorption Recycling and High-Value Reutilization of Heavy-Metal Ions from Wastewater: As a High-Performance Anode Lithium Battery

被引:8
作者
An, Yuhong [1 ]
Zhang, Wanqi [1 ]
Zhang, Xiaotao [2 ,3 ,5 ]
Zhong, Yuan [1 ]
Ding, Lijun [2 ]
Hao, Yinan [1 ,3 ]
White, Marshall [4 ]
Chen, Zhangjing [4 ]
An, Zhen [1 ]
Wang, Ximing [1 ,3 ,5 ]
机构
[1] Inner Mongolia Agr Univ, Coll Mat Sci & Art Design, Hohhot 010018, Peoples R China
[2] Inner Mongolia Agr Univ, Coll Sci, Hohhot 010018, Peoples R China
[3] Inner Mongolia Key Lab Sandy Shrubs Fibrosis & En, Hohhot 010018, Peoples R China
[4] Virginia Polytech Inst & State Univ, Dept Sustainable Biomat, Blacksburg, VA 24060 USA
[5] Natl Forestry Grassland Engn Technol Res Ctr Effi, Hohhot 010018, Peoples R China
关键词
LIGNOCELLULOSE AEROGELS; BIOMASS;
D O I
10.1021/acs.langmuir.3c01275
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The dazzling adsorbent products make people overlook the harm of heavy metals adsorbed on them. Hazardous waste adsorbents cause secondary pollution. In this study, waste lignocellulose was dissolved by alkaline urea solvent and high-intensity ultrasound, then cross-linked by epichlorohydrin to make hydrogel, which was utilized to adsorb toxic heavy-metal wastewater. In situ deposition and high-temperature carbonization turn the gel that has absorbed heavy metals into carbon aerogel-loaded metal oxide energy storage materials that may be employed as anodes in lithium-ion batteries with excellent electrochemical performance. The best reversible capacity was 435.86 mAh g-1 after 100 cycles at 0.2C, indicating that the hazardous solid waste generated by the removal of heavy metals using biomass-based adsorbent has potential lithium battery applications. Thus, we provide a fresh perspective on the efficient recycling of heavy metals as well as an environmentally friendly, high-value conservation strategy for lowering the danger of heavy-metal hazardous wastes.
引用
收藏
页码:12324 / 12335
页数:12
相关论文
共 38 条
[1]   High capacity Hg(II) and Pb(II) removal using MOF-based nanocomposite: Cooperative effects of pore functionalization and surface-charge modulation [J].
Abdollahi, Nasrin ;
Razavi, Sayed Ali Akbar ;
Morsali, Ali ;
Hu, Mao-Lin .
JOURNAL OF HAZARDOUS MATERIALS, 2020, 387
[2]   Biosorption of transition metals by freely suspended and Ca-alginate immobilised with Chlorella vulgaris: Kinetic and equilibrium modeling [J].
Ahmad, Ashfaq ;
Bhat, A. H. ;
Buang, Azizul .
JOURNAL OF CLEANER PRODUCTION, 2018, 171 :1361-1375
[3]   Role of surface functional groups of hydrogels in metal adsorption: From performance to mechanism [J].
Badsha, Mohammad A. H. ;
Khan, Musharib ;
Wu, Baile ;
Kumar, Ashutosh ;
Lo, Irene M. C. .
JOURNAL OF HAZARDOUS MATERIALS, 2021, 408
[4]   In-situ upcycling of cadmium from wastewater into core-shell ZnS@Zn0.58Cd0.42S heterojunction photocatalyst for environmental purification and H2 evolution [J].
Bi, Lei ;
Liu, Jingzhang ;
Du, Mei ;
Huang, Bang ;
Song, Maoyong ;
Jiang, Guibin .
CHEMICAL ENGINEERING JOURNAL, 2023, 454
[5]   Leveraging valuable synergies by combining alloying and conversion for lithium-ion anodes [J].
Bresser, Dominic ;
Passerini, Stefano ;
Scrosati, Bruno .
ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (11) :3348-3367
[6]   Gel-based nanocomposite using persulfate-activated bread crumbs for fulvic acid release and Pb(II) removal [J].
Cai, Dongqing ;
Yao, Xia ;
Wu, Qingchuan ;
Ye, Jinghong ;
Zhang, Jing ;
Guo, Minxue ;
Xu, He ;
Wang, Dongfang .
CHEMICAL ENGINEERING JOURNAL, 2022, 446
[7]   Recycling spent water treatment adsorbents for efficient electrocatalytic water oxidation reaction [J].
Chen, Zhijie ;
Zheng, Renji ;
Wei, Wenfei ;
Wei, Wei ;
Zou, Wensong ;
Li, Jing ;
Ni, Bing-Jie ;
Chen, Hong .
RESOURCES CONSERVATION AND RECYCLING, 2022, 178
[8]   Thiol-functionalized cellulose nanofiber membranes for the effective adsorption of heavy metal ions in water [J].
Choi, Hyeong Yeol ;
Bae, Jong Hyuk ;
Hasegawa, Yohei ;
An, Sol ;
Kim, Ick Soo ;
Lee, Hoik ;
Kim, Myungwoong .
CARBOHYDRATE POLYMERS, 2020, 234
[9]   Generalized Redox-Responsive Assembly of Carbon-Sheathed Metallic and Semiconducting Nanowire Heterostructures [J].
Choi, Sinho ;
Kim, Jieun ;
Hwang, Dae Yeon ;
Park, Hyungmin ;
Ryu, Jaegeon ;
Kwak, Sang Kyu ;
Park, Soojin .
NANO LETTERS, 2016, 16 (02) :1179-1185
[10]   Hierarchical structured porous N-doped carbon coating MnO microspheres with enhanced electrochemical performances as anode materials for lithium-ion batteries [J].
Gou, Qianzhi ;
Li, Chao ;
Zhong, Wanling ;
Zhang, Xueqi ;
Dong, Qiang ;
Lei, Caixia .
ELECTROCHIMICA ACTA, 2019, 296 :730-737