The influence of concentration variation on the spectroscopic behavior of Sm3+-doped zinc-lead-phosphates glasses for orange and reddish-orange light-emitting applications: experimental and Judd-Ofelt approach

被引：9

作者：

Okasha, Aly ^{[1
]}

Gaafar, M. S. ^{[2
]}

Marzouk, Samir Y. ^{[3
]}

机构：

[1] Natl Res Ctr, Phys Inst, Spect Dept, 33 ElBehouth St, Giza 12311, Egypt

[2] Natl Inst Stand, Ultrason Lab, Tersa Str,POB 136, Giza 12211, Egypt

[3] Arab Acad Sci & Technol, Fac Engn, Basic & Appl Sci, Cairo, Egypt

来源：

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2023年 / 34卷 / 05期

关键词：

GAMMA-RAY INTERACTIONS; OPTICAL-PROPERTIES; SM3+ IONS; FLUOROBORATE GLASSES; RADIATIVE PROPERTIES; DIELECTRIC-CONSTANT; OXIDE GLASSES; LUMINESCENCE; BASICITY; TEMPERATURE;

D O I：

10.1007/s10854-022-09677-6

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

A spectroscopy study was performed to investigate the absorption and emission behavior of zinc-lead phosphate-doped Sm3+ glasses sample. The parameters, density, rho, molar volume, V-m, samarium ion concentration N, and mean samarium ion separation, R were calculated. The absorption peaks were assigned and discussed. The band gap and Urbach's energies analysis were illustrated. The emission spectra and the emission lifetime decay were studied. The CIE diagram coordinate (0.393, 0.601) of the sample's emission was very close to the TV standard value. The oscillator strength f(cal) and f(exp) were calculated using Judd-Ofelt theory, and the model parameter trend was found to be omega(4) > omega(2) > omega(6) which indicates high glasses rigidity. The Absorption and emission cross-sections were studied and illustrated. The obtained optical parameters, absorption, and emission behaviors introduce the samples under investigation as a candidate for orange and reddish-orange photonic applications.

引用

页数：19

共 75 条

[11] Linear and nonlinear optical properties of simple oxides .2. [J].

Dimitrov, V ;

Sakka, S .

JOURNAL OF APPLIED PHYSICS, 1996, 79 (03) :1741-1745

[12] A COMMON OPTICAL BASICITY SCALE FOR OXIDE AND FLUORIDE GLASSES [J].

DUFFY, JA .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1989, 109 (01) :35-39

[13] INTERPRETATION OF GLASS CHEMISTRY IN TERMS OF OPTICAL BASICITY CONCEPT [J].

DUFFY, JA ;

INGRAM, MD .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1976, 21 (03) :373-410

[14] A REVIEW OF OPTICAL BASICITY AND ITS APPLICATIONS TO OXIDIC SYSTEMS [J].

DUFFY, JA .

GEOCHIMICA ET COSMOCHIMICA ACTA, 1993, 57 (16) :3961-3970

[15] UV-absorption and radiation effects in different glasses doped with iron and tin in the ppm range [J].

Ehrt, D .

COMPTES RENDUS CHIMIE, 2002, 5 (11) :679-692

[16] Gamma ray interactions with MoO3-doped lead phosphate glasses [J].

El Batal, F. H. ;

Abo-Naf, S. M. ;

Marzouk, S. Y. .

PHILOSOPHICAL MAGAZINE, 2011, 91 (03) :341-356

[17] Effect of heat treatment on the structural and optical properties of amorphous Sb2Se3 and Sb2Se2S thin films [J].

El-Sayad, E. A. ;

Moustafa, A. M. ;

Marzouk, S. Y. .

PHYSICA B-CONDENSED MATTER, 2009, 404 (8-11) :1119-1127

[18] Gamma ray interactions with undoped and CuO-doped lithium disilicate glasses [J].

Elbatal, H. A. ;

Mandouh, Z. ;

Zayed, H. ;

Marzouk, S. Y. ;

Elkomy, G. ;

Hosny, A. .

PHYSICA B-CONDENSED MATTER, 2010, 405 (23) :4755-4762

[19] Gamma rays interaction with copper doped lithium phosphate glasses [J].

ElBatal, Hatem A. ;

ElMandouh, Zeinab E. ;

Zayed, Hamdia A. ;

Marzouk, Samir Y. ;

Elkomy, Gihan M. ;

Hosny, Ahmed .

JOURNAL OF MOLECULAR STRUCTURE, 2013, 1054 :57-64

[20] Thermal, structure and morphological properties of lithium disilicate glasses doped with copper oxide and their glass-ceramic derivatives [J].

Elbatal, Hatem A. ;

Mandouh, Zeinab S. ;

Zayed, Hamdia A. ;

Marzouk, Samir Y. ;

Elkomy, Gihan M. ;

Hosny, Ahmed .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2012, 358 (15) :1806-1813

← 1 2 3 4 5 6 7 8 →