Catalytic Carbon Dioxide Fixation Reactions Based on Transition Metal Complexes and Their Systems

被引:14
作者
Iwasawa, Nobuharu [1 ]
机构
[1] Tokyo Inst Technol, 2-12-1 Ookayama,Meguro Ku, Tokyo 1528550, Japan
基金
日本科学技术振兴机构; 日本学术振兴会;
关键词
C-H BONDS; LIGHT-DRIVEN HYDROCARBOXYLATION; DIRECT CARBOXYLATION; ASYMMETRIC 1,4-ADDITION; ORGANOBORONIC ACIDS; BUILDING-BLOCK; ACRYLATE SALT; CO2; PALLADIUM; ARYL;
D O I
10.1246/bcsj.20230133
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this Account, transition metal-catalyzed carboxylation reactions developed in our laboratory are summarized according to the type of reaction. Design of new transition metal catalysts or catalyst systems is the essential part of the study and emphasis is placed on mechanistic aspects of the newly developed reactions, which have attracted our interest in this research.
引用
收藏
页码:824 / 841
页数:18
相关论文
共 105 条
[71]   Direct carboxylation of simple arenes with CO2 through a rhodium-catalyzed C-H bond activation [J].
Suga, Takuya ;
Mizuno, Hajime ;
Takaya, Jun ;
Iwasawa, Nobuharu .
CHEMICAL COMMUNICATIONS, 2014, 50 (92) :14360-14363
[72]   Catalytic Synthesis of a Methylmalonate Salt from Ethylene andCarbon Dioxide through Photoinduced Activation and Photoredox-Catalyzed Reduction of Nickelalactones [J].
Takahashi, Kohei ;
Sakurazawa, Yuji ;
Iwai, Asaki ;
Iwasawa, Nobuharu .
ACS CATALYSIS, 2022, 12 (07) :3776-3781
[73]   Mechanistic Investigations of the Ruthenium-Catalyzed Synthesis of Acrylate Salt from Ethylene and CO2 [J].
Takahashi, Kohei ;
Hirataka, Yo ;
Ito, Tatsuyoshi ;
Iwasawa, Nobuharu .
ORGANOMETALLICS, 2020, 39 (09) :1561-1572
[74]   Development of N-Phosphinomethyl-Substituted NHC-Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO2 [J].
Takahashi, Kohei ;
Cho, Kinryo ;
Iwai, Asaki ;
Ito, Tatsuyoshi ;
Iwasawa, Nobuharu .
CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (59) :13504-13508
[75]   Copper(I)-catalyzed carboxylation of aryl- and alkenylboronic esters [J].
Takaya, Jun ;
Tadami, Satoshi ;
Ukai, Kazutoshi ;
Iwasawa, Nobuharu .
ORGANIC LETTERS, 2008, 10 (13) :2697-2700
[76]   Synthesis, Structure, and Reactivity of a Mononuclear η2-(Ge-H)palladium(0) Complex Bearing a PGeP-Pincer-Type Germyl Ligand: Reactivity Differences between Silicon and Germanium [J].
Takaya, Jun ;
Iwasawa, Nobuharu .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (46) :5012-5018
[77]   Metallic reductant-free synthesis of α-substituted propionic acid derivatives through hydrocarboxylation of alkenes with a formate salt [J].
Takaya, Jun ;
Miyama, Ko ;
Zhu, Chuan ;
Iwasawa, Nobuharu .
CHEMICAL COMMUNICATIONS, 2017, 53 (28) :3982-3985
[78]   Silyl Ligand Mediated Reversible β-Hydrogen Elimination and Hydrometalation at Palladium [J].
Takaya, Jun ;
Iwasawa, Nobuharu .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (37) :11812-11819
[79]   Mechanistic Studies on the Stereoisomerization between Two Stereoisomeric, Isolable Five-Coordinate Borylpalladium(II) Complexes Bearing a Phenylene-Bridged PSiP-Pincer Type Ligand [J].
Takaya, Jun ;
Kirai, Naohiro ;
Iwasawa, Nobuharu .
ORGANOMETALLICS, 2014, 33 (06) :1499-1502
[80]   Synthesis, Structure, and Catalytic Activity of Palladium Complexes Bearing a Tridentate PXP-Pincer Ligand of Heavier Group 14 Element (X = Ge, Sn) [J].
Takaya, Jun ;
Nakamura, Shuhei ;
Iwasawa, Nobuharu .
CHEMISTRY LETTERS, 2012, 41 (09) :967-969