Catalytic Carbon Dioxide Fixation Reactions Based on Transition Metal Complexes and Their Systems

被引:14
作者
Iwasawa, Nobuharu [1 ]
机构
[1] Tokyo Inst Technol, 2-12-1 Ookayama,Meguro Ku, Tokyo 1528550, Japan
基金
日本科学技术振兴机构; 日本学术振兴会;
关键词
C-H BONDS; LIGHT-DRIVEN HYDROCARBOXYLATION; DIRECT CARBOXYLATION; ASYMMETRIC 1,4-ADDITION; ORGANOBORONIC ACIDS; BUILDING-BLOCK; ACRYLATE SALT; CO2; PALLADIUM; ARYL;
D O I
10.1246/bcsj.20230133
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this Account, transition metal-catalyzed carboxylation reactions developed in our laboratory are summarized according to the type of reaction. Design of new transition metal catalysts or catalyst systems is the essential part of the study and emphasis is placed on mechanistic aspects of the newly developed reactions, which have attracted our interest in this research.
引用
收藏
页码:824 / 841
页数:18
相关论文
共 105 条
[31]   Effect of Sodium Cation on Metallacycle b-Hydride Elimination in CO2- Ethylene Coupling to Acrylates [J].
Jin, Dong ;
Williard, Paul G. ;
Hazari, Nilay ;
Bernskoetter, Wesley H. .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (11) :3205-3211
[32]   Catalytic direct hydrocarboxylation of styrenes with CO2 and H2 [J].
Jin, Yushu ;
Caner, Joaquim ;
Nishikawa, Shintaro ;
Toriumi, Naoyuki ;
Iwasawa, Nobuharu .
NATURE COMMUNICATIONS, 2022, 13 (01)
[33]   Visible-Light-Enabled Carboxylation of Benzyl Alcohol Derivatives with CO2 Using a Palladium/Iridium Dual Catalyst [J].
Jin, Yushu ;
Toriumi, Naoyuki ;
Iwasawa, Nobuharu .
CHEMSUSCHEM, 2022, 15 (03)
[34]  
Johansson R, 2007, DALTON T, P488, DOI 10.1039/b614037h
[35]   Rhodium-Catalyzed Hydrocarboxylation of Olefins with Carbon Dioxide [J].
Kawashima, Shingo ;
Aikawa, Kohsuke ;
Mikami, Koichi .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 2016 (19) :3166-3170
[36]   PSiP-Pincer Type Palladium-Catalyzed Dehydrogenative Borylation of Alkenes and 1,3-Dienes [J].
Kirai, Naohiro ;
Iguchi, Shoichiro ;
Ito, Tatsuyoshi ;
Takaya, Jun ;
Iwasawa, Nobuharu .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2013, 86 (07) :784-799
[37]   Two Reversible σ-Bond Metathesis Pathways for Boron-Palladium Bond Formation: Selective Synthesis of Isomeric Five-Coordinate Borylpalladium Complexes [J].
Kirai, Naohiro ;
Takaya, Jun ;
Iwasawa, Nobuharu .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (07) :2493-2496
[38]   Reactions of an arylrhodium complex with aldehydes, imines, ketones, and alkynones. New classes of insertion reactions [J].
Krug, C ;
Hartwig, JF .
ORGANOMETALLICS, 2004, 23 (20) :4594-4607
[39]   The First Catalytic Synthesis of an Acrylate from CO2 and an Alkene-A Rational Approach [J].
Lejkowski, Michael L. ;
Lindner, Ronald ;
Kageyama, Takeharu ;
Bodizs, Gabriella E. ;
Plessow, Philipp N. ;
Mueller, Imke B. ;
Schaefer, Ansgar ;
Rominger, Frank ;
Hofmann, Peter ;
Futter, Cornelia ;
Schunk, Stephan A. ;
Limbach, Michael .
CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (44) :14017-14025
[40]   Recent advances in C-Si bond activation via a direct transition metal insertion [J].
Li, Linjie ;
Zhang, Yuebao ;
Gao, Lu ;
Song, Zhenlei .
TETRAHEDRON LETTERS, 2015, 56 (12) :1466-1473